| Oxidation of n-Butanol and 2-Pentanol with Molecular Oxygen in Supercritical CO2 |
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| 作者姓名： | YanHongCHANG TaoJIANG LiangGAO GuoYingZHAO HaiXianzGAO ZhongHaoLI JunChunLI ZhiMinLiu BuXingHAN |
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| 作者单位： | CenterforMolecularSciences,InstituteofChemistry,ChineseAcademyofSciences,Beijing100080 |
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| 摘 要： | Oxidation of n-butanol and 2-pentanol using molecular oxygen in supercritical (SC) CO2 with and without co-solvent is investigated. The results showed that the reaction selectivity is high when the reaction is carried out in SC CO2. It has been observed that co-solvent affects conversion and selectivity of the reaction considerably.
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| 关 键 词： | 氧化 n-丁醇 2-戊醇 分子氧 超临界二氧化碳 潜溶剂 |
Oxidation of n-Butanol and 2-Pentanol with Molecular Oxygen in Supercritical CO2 |
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| YanHongCHANG TaoJIANG LiangGAO GuoYingZHAO HaiXianzGAO ZhongHaoLI JunChunLI ZhiMinLiu BuXingHAN.Oxidation of n-Butanol and 2-Pentanol with Molecular Oxygen in Supercritical CO2[J].Chinese Chemical Letters,2003,14(10):1070-1072. |
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| Authors: | Yan Hong CHANG Tao JIANG Liang GAO Guo Ying ZHAO Hai Xiang GAO Zhong Hao LI Jun Chun LI Zhi Min LIU Bu Xing HAN |
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| Abstract: | Oxidation of n-butanol and 2-pentanol using molecular oxygen in supercritical (SC) CO2 with and without co-solvent is investigated. The results showed that the reaction selectivity is high when the reaction is carried out in SC CO2. It has been observed that co-solvent affects conversion and selectivity of the reaction considerably. |
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| Keywords: | Oxidation n-butanol 2-pentanol supercritical CO2 co-solvent |
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