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离子液体处理含油污水实验研究
引用本文:范洪富,马军.离子液体处理含油污水实验研究[J].燃料化学学报,2011,39(1):33-36.
作者姓名:范洪富  马军
作者单位:1.School of Energy Resource, China University of Geosciences, Beijing 100083, China,; 2.School of Municipal and Environmental Engineering, Harbin Institute of Technology, Harbin 150008, China
基金项目:国家教育部重点项目(207032)
摘    要:合成出了适合于含油污水处理的憎水性离子液体,研究了离子液体对含油污水的处理条件。当离子液体与含油污水体积比为1∶5,pH值为5,处理15min后,水中油的去除率为95.6%,CODCr的去除率为93.5%,表明应用离子液体可以有效地去除油田采出水中的有机物。同时考察了再生离子液体对除油效果的影响,其五次平行实验的除油率达95.4%,CODCr去除率为93.2%,表明离子液体可以回收利用。在此基础上,分析了离子液体对含油污水处理的作用机理。

关 键 词:  style="font-size:  9pt  line-height:  离子液体" target="_blank">150%">离子液体  油田污水  去除率  机理  
收稿时间:2010-03-17
修稿时间:2010-07-03

Application of ionic liquids in oilfield wastewater treatment
FAN Hong-fu,MA Jun.Application of ionic liquids in oilfield wastewater treatment[J].Journal of Fuel Chemistry and Technology,2011,39(1):33-36.
Authors:FAN Hong-fu  MA Jun
Institution:FAN Hong-fu1,MA Jun2(1.School of Energy Resource,China University of Geosciences,Beijing 100083,China,2.School of Municipal and Environmental Engineering,Harbin Institute of Technology,Harbin 150008,China)
Abstract:The hydrophobic ionic liquid, \BMIM\]\BF6\] was synthesized, and the treatment conditions were investigated. When the extraction ratio is 1∶5, and pH=5, after 15min, the oil removal ratio is 95.6% and the CODCr removal is 93.5%. At the same time, the recovery of ionic liquids experiment was carried out. By the recovery ionic liquid, the oil and CODCr removal were 95.4%and 93.2% respectively, the results showed that ionic liquid can be regenerated and the effects are not reduced. The results indicate that the hydrophobic ionic liquids can remove the oil and organic compounds in the oilfield wastewater effectively. And the mechanism of ionic liquids was proposed.
Keywords:ionic liquids  oilfield wastewater  removal ratio  mechanism  
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