| CO偶联-再生反应合成草酸二乙酯过程的模拟(英文) |
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| 引用本文： | 王保伟,马新宾,毛兰芳,许根慧.CO偶联-再生反应合成草酸二乙酯过程的模拟(英文)[J].天然气化学杂志,2000,9(3):187-196. |
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| 作者姓名： | 王保伟 马新宾 毛兰芳 许根慧 |
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| 作者单位： | 天津大学化工学院一碳化工国家重点实验室!天津 300072，天津大学化工学院一碳化工国家重点实验室!天津 300072，天津大学化工学院一碳化工国家重点实验室!天津 300072，天津大学化工学院一碳化工国家重点实验室!天津 300072 |
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| 基金项目： | the Ninth Five-year Plan Subject of China. |
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| 摘 要： | 采用序贯模块法ＡＳＰＥＮ、ＰＲＯ／Ⅱ及二维拟均相气固反应器和鼓泡塔气液反应器模型的程序对ＣＯ气相偶联合成草酸二乙酯两步反应循环系统进行模拟和调优，同时考察了各种操作条件对整个系统的影响，计算出适宜的操作范围。模拟结果与模实验数据进行了显著性检验，其置信度为 ９５％。
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| 关 键 词： | 一氧化碳 偶联-再生反应 草酸二乙酯 模拟 |
SIMULATION OF THE PROCESS OF DIETHYL OXALATE PREPARED BY CO COUPLINGREGENERATION REACTION |
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| Baowei Wang,Xinbin Ma,Lanfang Mao,Genhui Xu.SIMULATION OF THE PROCESS OF DIETHYL OXALATE PREPARED BY CO COUPLINGREGENERATION REACTION[J].Journal of Natural Gas Chemistry,2000,9(3):187-196. |
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| Authors: | Baowei Wang Xinbin Ma Lanfang Mao Genhui Xu |
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| Institution: | School of Chemical Engineering, State Key Lab. C1 Chem. Tech., Tianjin University Tianjin 300072 |
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| Abstract: | The steady-state simulation and optimization were carried out for the synthesis of diethyl oxalate by CO coupling regeneration in gaseous phase by using Sequential Modular Approach software ASPEN, PRO/II and programs for two-dimension quasi-homogeneous reactor and gas-liquid turbulent bubble column reactor. At the same time, the effects of various operating parameters were examined and the optimal operation conditions were determined. And also the simulation results and the experimental results were compared and the accuracy is 95%. |
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| Keywords: | diethyl oxalate CO coupling-regeneration simulation |
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