| 金属富勒烯La＠C_（2n）的合成、提取及其ESR和MS表征 |
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| 引用本文： | 刘冰冰,徐文国,刘子阳,杨海滨,李明辉,刘淑莹,邹广田.金属富勒烯La＠C_（2n）的合成、提取及其ESR和MS表征[J].高等学校化学学报,1996(5). |
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| 作者姓名： | 刘冰冰 徐文国 刘子阳 杨海滨 李明辉 刘淑莹 邹广田 |
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| 作者单位： | 吉林大学超硬材料国家重点实验室，吉林大学化学系，中国科学院长春应用化学研究所 |
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| 基金项目： | 国家自然科学基金,中国科学院稀土物理与化学开放实验室资助 |
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| 摘 要： | 采用对掺入Ｌａ_２Ｏ_３的石墨棒原位活化并结合交换电极回放方法制备了产率较高的金属富勒烯，并用甲苯高温热提取的方法有效地提取出Ｌａ＠Ｃ_（２ｎ），其中Ｌａ＠Ｃ_（７４）为可溶性金属富勒烯增加了新成员．同时，首次采用解吸电子轰击质谱对提取物进行了表征，讨论了提取物的ＥＳＲ谱．
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| 关 键 词： | 金属富勒烯La＠C_（2n），甲苯高温热提取，DEI质谱，ESR谱 |
Synthesis and Extraction of Lanthanofullerenes and Its DEIMS, ESR Characterizations |
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| LIU Bhg-Bhg, XU Wen-Guo, LIU Zi-Yang, YANG Hai-Bin,LI Ming-Hui, LIU Shu-Ying, ZOU Guang-Tian.Synthesis and Extraction of Lanthanofullerenes and Its DEIMS, ESR Characterizations[J].Chemical Research In Chinese Universities,1996(5). |
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| Authors: | LIU Bhg-Bhg XU Wen-Guo LIU Zi-Yang YANG Hai-Bin LI Ming-Hui LIU Shu-Ying ZOU Guang-Tian |
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| Abstract: | The synthesis for lanthanofullerenes was studied by activating the La_2O_a containing graphite rod in situ and back-burning the carbide-rich cathode deposite, La@C_(2n) are efficiently extracted in high temperature toluene, among them, La@C_(74) as a new species is added into the soluble lanthanofullerenes, The toluene extraction is first characterized by desorption electron impact(DEI)mass spectrometry, The ESR spectrum of the extraction at room temperature is also discussed. |
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| Keywords: | Lanthanofullerenes La@C_(2n) High temperature toluene extraction DEI MS ESR spectrum |
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