| 微波辅助固相有机反应 |
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| 引用本文： | 喻爱明,张政朴,杨华铮,张春香,刘准.微波辅助固相有机反应[J].高等学校化学学报,1998,19(10):1608-1610. |
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| 作者姓名： | 喻爱明 张政朴 杨华铮 张春香 刘准 |
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| 作者单位： | 1. 南开大学元素有机化学国家重点实验室, 天津, 300071;
2. 南开大学吸附分离功能高分子材料国家重点实验室, 天津, 300071 |
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| 摘 要： | 固相有机合成是组合化学中构建化合物库的主要工具之一［１，２］，但是，由于它是连接在固相载体（如树脂等）上的试剂与溶解在有机溶剂中的试剂之间的反应，因此反应比较缓慢．考虑到微波技术对有机反应的协助作用，我们将微波技术应用到固相有机反应中，对比研究了微波...
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| 关 键 词： | 固相有机反应 微波照射 FTIR 树脂微球 |
| 收稿时间： | 1997-09-17 |
Microwave Assisting Solid Phase Organic Reaction Monitored by FTIR |
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| YU Ai-Ming,ZHANG Zheng-Pu,YANG Hua-Zheng,ZHANG Chun-Xiang,LIU Zhun.Microwave Assisting Solid Phase Organic Reaction Monitored by FTIR[J].Chemical Research In Chinese Universities,1998,19(10):1608-1610. |
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| Authors: | YU Ai-Ming ZHANG Zheng-Pu YANG Hua-Zheng ZHANG Chun-Xiang LIU Zhun |
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| Institution: | 1. State Key Laboratory of Elemento Organic Chemistry, Nankai University, Tianjin, 300071;
2. State Key Laboratory of Functional Polymeric Materials for Adsorption and Separation, Nankai University, Tianjin, 300071 |
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| Abstract: | Microwave assisting the addition reaction of Wang resin bound secondary amine 1 and isocyanate was carried out for the first time. The reaction time course was determined by analyzing FTIR spectra obtained using the improved KBr pellet method by grinding down the resin beads prior to recording. The results showed that the reaction assisted by microwave was accomplished only in 12 min, while the reaction without microwave was completed in 210 min. |
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| Keywords: | Solid phase organic reaction Microwave irradiation FTIR Resin beads |
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