Two Self‐assembled Water Clusters Stabilized by Cu‐containing Compounds Based on MoO42– |
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| Authors: | Ye Kuang Bing Yang Jiali Pan Xianggao Meng Fengping Xiao |
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| Institution: | Department of Chemistry, Central China Normal University, 152 Luoyu Road, Hongshan District, 430079 Wuhan, P. R. China |
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| Abstract: | Two copper‐containing compounds based on MoO42–, Cu4(phen)4(μ2‐OH)2(μ3‐OH)2(H2O)2]MoO4]2 · 10H2O ( 1 ) and Cu(phen)2Mo2O7(phen)] · 8H2O ( 2 ) (phen = 1,10‐phenanthroline), were hydrothermally synthesized. In the crystal lattices of 1 and 2 , discrete octameric water cycles and 2D layer water clusters were observed. The cyclic water octamer clusters exist stably in the channels constructed by Cu4(phen)4(OH)4(H2O)2]2+ and MoO42– by hydrogen bonds in 1 at low temperature and 2D layer water clusters are formed by (H2O)16 units in 2 . |
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| Keywords: | Octameric water cycle 2D layer water cluster Copper Molybdate |
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