| Synthesis,Structure and Luminescent Property of a New bnn-type Zn(Ⅱ) Coordination Polymer |
| |
| 引用本文： | 宋美月,黄园园,张鑫,姚元根.Synthesis,Structure and Luminescent Property of a New bnn-type Zn(Ⅱ) Coordination Polymer[J].结构化学,2014,33(8):1222-1226. |
| |
| 作者姓名： | 宋美月 黄园园 张鑫 姚元根 |
| |
| 作者单位： | [1]Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Fujian Instituteof Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China; [2]University of Chinese Academy of Sciences, Beijing 100039, China |
| |
| 基金项目： | supported by the 973 Program of China(2011CBA00505);National Key Technology R&D Program(2012BAE06B08);the Chinese Academy of Sciences(KJCX2-YW-H30);the Science Foundation of Fujian Province(2009HZ0005-1) |
| |
| 摘 要： | A new Zn(Ⅱ) coordination polymer, namely Zn(Htci)(bib)0.5(H2O)]n·nH2O(1, H3 tci = tri(2-carboxyethyl)isocyanurate, bib = 1,4-bis(imidazol-1-ylmethyl)-butane) has been synthesized by combining H3 tci and bib ligands with Zn(Ⅱ) salts under solvothermal conditions. The title compound crystallizes in monoclinic, space group P21/c with a = 13.3424(7), b = 7.9051(5), c = 20.4650(12) , β = 101.935(5)o, V = 2111.8(2) 3, C17H24N5O11 Zn, Mr = 539.8, Z = 4, Dc = 1.698 g/cm3, F(000) = 1116, μ = 1.236 mm-1, the final R = 0.0398 and wR = 0.00879 for 3722 observed reflections(I 2■(I)). X-ray structural analysis reveals that compound 1 exhibits a three-dimensional(3D) pillar-layered framework, and can be simplified into a 5-connected bnn topological network. Moreover, the luminescent properties for compound 1 were also studied at room temperature.
|
| 关 键 词： | X射线结构分析 配位聚合物 BNN 荧光性质 合成 标题化合物 锌 N型 |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
