| A Dinuclear Zinc(Ⅱ) Complex Derived from a ‘Click' Ligand Containing Phenol,Pyridine and Triazole Donors |
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| 引用本文： | 游秀丽,魏振宏.A Dinuclear Zinc(Ⅱ) Complex Derived from a ‘Click' Ligand Containing Phenol,Pyridine and Triazole Donors[J].结构化学,2014,33(7):1007-1012. |
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| 作者姓名： | 游秀丽 魏振宏 |
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| 作者单位： | [1]Department of Chemistry, Nanchang University, Nanchang 330013, China; [2]Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang 330013, China |
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| 基金项目： | Financially supported by the Education Department of Jiangxi Province(GJJ13106) |
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| 摘 要： | A novel 1,2,3-triazolyl-containing ligand(H2L) with long donor arms extending from the central pyridyl linker was synthesized by click cycloaddition of 2,6-bis(azidomethyl)pyridine and 2-((prop-2-yn-1-yl(pyridin-2-ylmethyl)amino)methyl)phenol. Further treatment of the ligand H2 L with zinc(Ⅱ) perchlorate in the presence of triethylamine, followed by anion exchange with NaBPh4], provided a dinuclear zinc(Ⅱ) complex Zn2L]BPh4]2·2DMF(1). Complex 1 crystallizes in monoclinic, space group P21 with a = 10.4873(4), b = 14.9078(5), c = 25.8620(9) A, β = 94.566(2)o, V = 4030.5(2) A3, Z = 2, μ = 0.657 mm-1, Dc = 1.324 Mg/m3, T = 296(2) K, C93H91N13B2O4Zn2, Mr = 1607.19, F(000) = 1684, S = 0.958, R = 0.0271 and wR = 0.0607. In the structure of cation, the phenolate oxygen atoms of ligand act as the bridging nodes to form a rhombic Zn2(OAr)2 core.
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| 关 键 词： | 三唑基 苯酚 配体 吡啶 双核 锌 阴离子交换 高氯酸盐 |
A Dinuclear Zinc(Ⅱ) Complex Derived from a ‘Click' Ligand Containing Phenol,Pyridine and Triazole Donors |
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| YOU Xiu-Li
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WEI Zhen-Hong.A Dinuclear Zinc(Ⅱ) Complex Derived from a ‘Click' Ligand Containing Phenol,Pyridine and Triazole Donors[J].Chinese Journal of Structural Chemistry,2014,33(7):1007-1012. |
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| Authors: | YOU Xiu-Li WEI Zhen-Hong |
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| Institution: | 1. Department of Chemistry, Nanchang University, Nanchang 330013, China;Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang 330013, China
2. Department of Chemistry, Nanchang University, Nanchang 330013, China |
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| Abstract: | multidentate ligand, dinucleaf zinc complex, hydroxyl group, crystal structure |
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| Keywords: | multidentate ligand dinuclear zinc complex hydroxyl group crystal structure |
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