| Synthesis,Structure and Norbornene Polymerization Catalyzed by o-Benzene Diimine Di-nuclear Palladium(Ⅱ) Complex |
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| 作者姓名： | LI Chao LAN Mei-Ying MENG Su-Qin CHEN Jian-Xin ZHANG Zhi-Chun |
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| 作者单位： | [1]College of Chemistry and Chemical Engineering, Fujian Normal University, Fuzhou 350G07, China [2]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China |
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| 基金项目： | This work was supported by the Natural Science Foundation of Fujian Province （2010J01026）, the Ministry of Education of China （No.208066）, the Education Department of Fujian Province （JA07029）, and the State Key Laboratory of Structural Chemistry （No. 20130013） |
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| 摘 要： | The title complex, C20H17N4Pd2Cl3·0.5CH3OH, crystallizes in the triclinic system, space group P1 with a = 9.927(6), b = 11.079(6), c = 11.233(6) ?, α = 73.970(12), β = 85.738(16), γ = 83.300(12)o, V = 1178.1(11)?3, Mr = 648.55, Z = 2, Dc = 1.520 g/cm3, μ = 1.884 mm-1, F(000) = 634, the final R = 0.0460 and wR = 0.1280. This title compound was investigated for the catalytic behavior towards norbornene(NB) vinyl addition polymerization. And the complex exhibits good catalytic activity to catalyze norbornene polymerization using MAO as a cocatalyst.
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| 关 键 词： | 降冰片烯 催化性能 加成聚合 邻苯二亚胺 配合物 标题化合物 合成 双核 |
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