| Hydrothermal Synthesis, Crystal Structure and Photoluminescent Property of a Novel Complex [Zn（OHCT）（1,2-BDC）]_n |
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| 引用本文： | 李传碧,杨宇,张首才,闫丽,李晶,孙丽娟,李文成,王家军.Hydrothermal Synthesis, Crystal Structure and Photoluminescent Property of a Novel Complex [Zn（OHCT）（1,2-BDC）]_n[J].结构化学,2011,30(9):1233-1238. |
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| 作者姓名： | 李传碧 杨宇 张首才 闫丽 李晶 孙丽娟 李文成 王家军 |
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| 作者单位： | Chemistry College of Jilin Normal University;Key Laboratory of Preparation and Applications of Environmental Friendly Materials (MOE);Jilin Normal University; |
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| 摘 要： | A novel ligand 11-oxa-4,5,9,10,12,13-hexaaza-cyclopenta b] triphenylene (OHCT) and its coordination polymer Zn(OHCT)(1,2-BDC)]n 1 (1,2-BDC = 1,2-benzenedicarboxylate) were synthesized and characterized. Crystallographic data for OHCT: C14H6N6O5, Mr = 274.25, monoclinic, space group P21/c, a = 10.755(3), b = 11.710(4), c = 9.516(3) , β = 108.457(4)o, V = 1136.9(6) 3, Dc = 1.602 g/cm3, μ(MoKα) = 0.111 mm-1, F(000) = 560, Z = 4, the final R = 0.1534 and wR = 0.39709. Crystallographic data for 1: C22H10ZnN6O5, Mr = 503.73, triclinic, space group P , a = 6.1411(5), b = 10.9111(9), c = 14.1925(1) , α = 89.1830(1), β = 79.3030(1), γ = 84.6350(1)o, V = 930.36(1) 3, Dc = 1.798 g/cm3, μ(MoKα) = 1.376 mm-1, F(000) = 508, Z = 2, the final R = 0.0323 and wR = 0.0789. 1 has been obtained by using hydrothermal synthesis and characterized by elemental analysis, IR spectrum, thermal analysis, fluorescence spectrum and single-crystal X-ray diffraction. In complex 1, the zinc atom is five-coordinated with three carboxylate oxygen atoms from three different 1,2-BDC ligands and two nitrogen atoms from one OHCT ligand, showing a distorted trigonal bipyramidal configuration.
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| 关 键 词： | 水热合成 BDC 晶体结构 复合发光 物业 锌 苯二甲酸 氧原子 |
Hydrothermal Synthesis, Crystal Structure and Photoluminescent Property of a Novel Complex [Zn(OHCT)(1,2-BDC)]_n |
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| LI Chuan-Bi
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YANG Yu
,
ZHANG Shou-Cai
,
YAN Li
,
LI Jing
,
SUN Li-Juan
,
LI Wen-Cheng
,
WANG Jia-Jun.Hydrothermal Synthesis, Crystal Structure and Photoluminescent Property of a Novel Complex [Zn(OHCT)(1,2-BDC)]_n[J].Chinese Journal of Structural Chemistry,2011,30(9):1233-1238. |
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| Authors: | LI Chuan-Bi YANG Yu ZHANG Shou-Cai YAN Li LI Jing SUN Li-Juan LI Wen-Cheng WANG Jia-Jun |
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| Institution: | Chemistry College of Jilin Normal University, Siping, Jilin 136000, China／Key Laboratory of Preparation and Applications of Environmental Friendly Materials （MOE）, Jilin Normal University, Siping, Jilin 136000, China |
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| Abstract: | A novel ligand 11-oxa-4,5,9,10,12,13-hexaaza-cyclopenta b] triphenylene (OHCT) and its coordination polymer Zn(OHCT)(1,2-BDC)]n 1 (1,2-BDC = 1,2-benzenedicarboxylate) were synthesized and characterized. Crystallographic data for OHCT: C14H6N6O5, Mr = 274.25, monoclinic, space group P21/c, a = 10.755(3), b = 11.710(4), c = 9.516(3) , β = 108.457(4)o, V = 1136.9(6) 3, Dc = 1.602 g/cm3, μ(MoKα) = 0.111 mm-1, F(000) = 560, Z = 4, the final R = 0.1534 and wR = 0.39709. Crystallographic data for 1: C22H10ZnN6O5, Mr = 503.73, triclinic, space group P , a = 6.1411(5), b = 10.9111(9), c = 14.1925(1) , α = 89.1830(1), β = 79.3030(1), γ = 84.6350(1)o, V = 930.36(1) 3, Dc = 1.798 g/cm3, μ(MoKα) = 1.376 mm-1, F(000) = 508, Z = 2, the final R = 0.0323 and wR = 0.0789. 1 has been obtained by using hydrothermal synthesis and characterized by elemental analysis, IR spectrum, thermal analysis, fluorescence spectrum and single-crystal X-ray diffraction. In complex 1, the zinc atom is five-coordinated with three carboxylate oxygen atoms from three different 1,2-BDC ligands and two nitrogen atoms from one OHCT ligand, showing a distorted trigonal bipyramidal configuration. |
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| Keywords: | zinc（Ⅱ） complex crystal structure fluorescence thermal property |
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