Synthesis and Structure of 1.5Zn(phen)3·L·3NO3 Supramolecule (phen = o-Phenanthroline,L = 4-Aminoacetophenone Thiosemicarbazone) |
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作者姓名: | ZHANG Nian-You LI Quan-Jun LIU Ying-Ying |
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作者单位: | Key Lab for Polyoxometalate Science, Department of Chemistry, Northeast Normal University, Changchun 130024, China |
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基金项目: | This work was supported by the Science Foundation for Young Teachers of NENU (No. 20070314) |
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摘 要: | A supramolecular framework, 1.5Zn(phen)3·L·3NO3 (C63H48Zn1.5N16O9S), has been synthesized. The ligand L was synthesized by the condensation of p-aminoacetophenone with thiosemicarbazide. The crystal belongs to the monoclinic system, space group C2/c, with a = 31.005(2), b = 15.114(2), c = 24.887(3) A, β = 94.260(2)° Z = 8, V = 11630(2)A^3 Dc = 1.489 g/cm^3, Mr = 1303.29,λ(MoKa) = 0.71069 A,μ= 0.735 mm^-1, F(000) = 5368, Rint = 0.0699, R= 0.0505 and wR= 0.0707. Two independent Zn atoms are both coordinated by six N atoms from three phen ligands. π-π and C-H…π interactions among the L ligands and Zn(phen)3 cations, π-π and C-H...π interactions among the Zn(phen)3 cations and N-H...O hydrogen bonds among the L ligands and nitrate anions connect the whole structure into a 3-D supramolecular framework.
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关 键 词: | 合成 晶体结构 锌 苯基 缩氨基硫脲 |
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