1. Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190 (China), Fax: (+86)?10‐8254‐3580;2. Center of Super‐Diamond and Advanced Films (COSDAF);3. Department of Physics and Materials Science, City University of Hong Kong, Hong Kong SAR (China)
Abstract:
A new class of tetrathiafulvalene‐based microstructures fabricated by coordinative self‐assembly has been prepared by a solution process. Upon incorporation of Pb2+ and Zn2+ ions, 1D wirelike microstructures and spherical polymer particles were achieved, respectively (see picture). The neutral coordination polymers are conductive and magnetic at room temperature without external manipulation.