| 不同Pt-SnO2制备工艺对乙醇燃料电池性能影响 |
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| 引用本文： | 刘万辉,惠洋,顾渊铠,房志远,殷敏豪,王旭红.不同Pt-SnO2制备工艺对乙醇燃料电池性能影响[J].化学通报,2018,81(1):70-76. |
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| 作者姓名： | 刘万辉 惠洋 顾渊铠 房志远 殷敏豪 王旭红 |
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| 作者单位： | 常熟理工学院化学与材料工程学院,常州大学材料科学与工程学院,常熟理工学院化学与材料工程学院,常熟理工学院化学与材料工程学院,常熟理工学院化学与材料工程学院,常州大学材料科学与工程学院 |
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| 基金项目： | 江苏省高校自然科学研究项目(15KJD430002) |
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| 摘 要： | 本文在石墨烯改性碳纤维的基础上,通过添加聚偏氟乙烯(PVDF)造孔、浸渍法、水热法制备出不同的Pt-SnO2/改性碳纤维阳极催化剂。以扫描电镜(SEM)、X射线衍射仪(XRD)、拉曼光谱图、电催化性能、单电池发电性能等手段来表征和测试,结果表明添加PVDF造孔后催化剂催化性能最好,峰电流密度可达137.33mA.cm-2,其电阻也明显减少,当制备成单电池时也具有最高功率密度,为22.89 mW.cm-2。
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| 关 键 词： | 燃料电池 阳极催化剂 造孔 浸渍法 水热法 |
| 收稿时间： | 2017/5/9 0:00:00 |
| 修稿时间： | 2017/9/16 0:00:00 |
Effect of Different Pt-SnO2Preparation Process on Ethanol Fuel Cell Performance |
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| LIU Wanhui,HUI Yang,GU Yuankai,FANG Zhiyuan,YIN Minhao and WANG Xuhong.Effect of Different Pt-SnO2Preparation Process on Ethanol Fuel Cell Performance[J].Chemistry,2018,81(1):70-76. |
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| Authors: | LIU Wanhui HUI Yang GU Yuankai FANG Zhiyuan YIN Minhao and WANG Xuhong |
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| Institution: | School of Chemistry and Materials Engineering,Changshu Institute of Technology,School of materials science and engineering,Changzhou University,School of Chemistry and Materials Engineering,Changshu Institute of Technology,School of Chemistry and Materials Engineering,Changshu Institute of Technology,School of Chemistry and Materials Engineering,Changshu Institute of Technology,School of materials science and engineering,Changzhou University |
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| Abstract: | Based on the modified carbon fiber of graphene, different Pt-SnO2/ modified carbon fiber anode catalysts were prepared by adding poly vinylidene fluoride (PVDF), impregnating method and hydrothermal method. The physical and chemical properties of the cathode catalysts were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), raman spectra, electric catalytic properties, single battery power performance and so on. The results showed that after adding PVDF pore-forming catalytic performance is best, the peak current density of 137.33mA·cm-2, its resistance also decreased significantly, when preparation into a single battery also has the highest power density of the four methods, 22.89 mW·cm-2. |
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| Keywords: | fuel cell anode catalyst pore hydrothermal reduction impregnation |
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