| 金刚烷胺邻香兰素Schiff碱过渡金属配合物的合成与表征 |
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| 引用本文： | 赵国良,吕天喜,刘卫东,胡晓春.金刚烷胺邻香兰素Schiff碱过渡金属配合物的合成与表征[J].化学研究,2006,17(4):28-30,34. |
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| 作者姓名： | 赵国良 吕天喜 刘卫东 胡晓春 |
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| 作者单位： | 浙江师范大学,化学与生命科学学院,浙江,金华,321004 |
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| 摘 要： | 合成了金刚烷胺邻香兰素Sch iff碱配体(C18H23NO2,以L表示)与过渡金属的6种新的配合物MC l2L](M=Mn(Ⅱ),Co(Ⅱ),N i(Ⅱ),Cu(Ⅱ),Zn(Ⅱ),Cd(Ⅱ)),用元素分析、摩尔电导、红外光谱和热重分析表征了配合物的结构;讨论了配体与中心金属离子的键合情况并推测了配合物的结构,每一中心金属离子与Sch iff碱配体中的酚羟基氧、甲氧基氧及2个氯离子发生配位,其配位数为4.
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| 关 键 词： | 金刚烷胺 邻香兰素 Schiff碱 过渡金属 配合物 |
| 文章编号： | 1008-1011（2006）04-0028-03 |
| 收稿时间： | 2006-07-29 |
| 修稿时间： | 2006年7月29日 |
Syntheses and Characterization of Transition Metal Complexes of Schiff Base Derived from Adamantaneamine and o-Vanillin |
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| ZHAO Guo-liang,L Tian-xi,LIU Wei-dong,HU Xiao-chun.Syntheses and Characterization of Transition Metal Complexes of Schiff Base Derived from Adamantaneamine and o-Vanillin[J].Chemical Research,2006,17(4):28-30,34. |
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| Authors: | ZHAO Guo-liang L Tian-xi LIU Wei-dong HU Xiao-chun |
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| Institution: | ZHAO Guo-liang,L(U) Tian-xi,LIU Wei-dong,HU Xiao-chun |
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| Abstract: | Six newsolid complexes were synthesized from tranisition metals with a Schiff base(C18H23NO2,L) derived fromadamantaneamine ando-vanillin,and characterized by elemental analysis,molarconductance,infrared spectra,thermal analysis.Their chemical formula are MCl2L](M=Mn(Ⅱ),Co(Ⅱ),Ni(Ⅱ),Cu(Ⅱ),Zn(Ⅱ),Cd(Ⅱ)).The coordination modes of the bonding in these com-plexes were discussed and the possible structures were proposed.Every central M(Ⅱ) ion in the com-plexes coordinates with a Schiff base ligand via two oxygen atoms of the phenol hydroxy group,methoxygroup and two chloride anions.The coordination number is four. |
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| Keywords: | adamantaneamine o-vanillin Schiff base transition metal complex |
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