| 水杨醛缩糠胺合钴（Ⅲ）配合物的合成,表征与晶体结构 |
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| 引用本文： | 孙鹏,王剑,常领,张武,何民会.水杨醛缩糠胺合钴（Ⅲ）配合物的合成,表征与晶体结构[J].化学研究,2009,20(1):9-11. |
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| 作者姓名： | 孙鹏 王剑 常领 张武 何民会 |
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| 作者单位： | 1. 河南大学,化学化工学院,分子与晶体工程研究所,河南,开封,475004
2. 河南省商丘市第二高级中学,河南,商丘,476100 |
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| 摘 要： | 合成了水杨醛缩糠胺合钴（Ⅲ）配合物Co（SF）3HSF=水杨醛缩糠胺Schiff碱],通过IR和单晶X射线衍射测定了其结构.配合物属三斜晶系,空间群P墿,晶体学参数a=0.900 64（8）nm,b=1.061 13（9）nm,c=1.636 23（14）nm,α=93.989 0（10）°,β=94.886 0（10）°,γ=93.627 0（10）°.分子式C36H30CoN3O6,V=1.550 5（2）nm3,Z=2,Dc=1.413 g/cm3,F（000）=684,R1=0.0350,wR2=0.0958I〉2sigma（I）],S=1.068.在配合物分子中,Co原子处于三个N原子、三个酚O原子形成的变形八面体场中.
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| 关 键 词： | 水杨醛 糠胺 Schiff碱 钴 配合物 晶体结构 |
Synthesis, Characterization and Crystal Structure of Tri(Salicylidenefurfurylaminato)Cobalt(Ⅲ) |
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| SUN Peng,WANG Jian,CHANG Ling,ZHANG Wu,HE Min-hui.Synthesis, Characterization and Crystal Structure of Tri(Salicylidenefurfurylaminato)Cobalt(Ⅲ)[J].Chemical Research,2009,20(1):9-11. |
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| Authors: | SUN Peng WANG Jian CHANG Ling ZHANG Wu HE Min-hui |
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| Institution: | SUN Peng, WANG Jian, CHANG Ling, ZHANG Wu, HE Min-hui ( 1. hitute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004 Henan, China; 2. Shangqiu Second High Middle School, Shangqiu 476100, Henan, China) |
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| Abstract: | The title complex Co(SF)3 HSF=salicylidenefurfurylamine] was synthesized and characterized by IR and single crystal X-ray diffraction.It crystallizes in triclinic system,space group Pī,with a=0.900 64(8) nm,b=1.061 13(9) nm,c=1.636 23(14) nm,α=93.989 0(10)°,β=94.886 0(10)°,γ=93.627 0(10)°.Molecular formular: C36H30CoN3O6,V=1.550 5(2) nm3,Z=2,Dc=1.413 g/cm3,F(000)=684,R1=0.035 0,wR2=0.095 8 I>2sigma(I)],S=1.068.The cobalt(Ⅲ) atom is coordinated by three nitrogen atoms and three phenolate oxygen atoms in a distorted octahedron. |
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| Keywords: | salicylaldehyde furfurylamine Schiff base cobalt complex crystal structure |
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