| 脱氢枞酸降解胺Schiff碱及其铜(Ⅱ)配合物的合成与表征 |
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| 引用本文： | 崔国友,莫炳荣,陈文纳.脱氢枞酸降解胺Schiff碱及其铜(Ⅱ)配合物的合成与表征[J].化学研究,2006,17(4):21-23. |
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| 作者姓名： | 崔国友 莫炳荣 陈文纳 |
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| 作者单位： | 1. 广西师范学院,化学系,广西,南宁,530001
2. 广西化工研究院,广西,南宁,530001 |
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| 基金项目： | 广西青年科学基金(0542016)资助项目 |
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| 摘 要： | 由水杨醛合成了四种取代水杨醛:5-溴水杨醛、5-氯水杨醛、5-硝基水杨醛、3,5-二硝基水杨醛,用从歧化松香中分离出的纯净的脱氢枞酸先合成脱氢枞酸酰氯,通过Curtius重排转化成脱氢枞酸降解胺,利用水杨醛和取代水杨醛与脱氢枞酸降解胺合成了五种Sch iff碱,并与铜离子配合制得铜配合物.用红外、核磁和元素分析进行了分析.
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| 关 键 词： | 脱氢枞酸降解胺 水杨醛 Schiff碱 铜配合物 |
| 文章编号： | 1008-1011（2006）04-0021-03 |
| 收稿时间： | 2006-09-07 |
| 修稿时间： | 2006年9月7日 |
Synthesis and Characterization of Dehydroabietylamine Schiff Bases and Copper(Ⅱ) Complexes |
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| CUI Guo-you,MO Bing-rong,CHEN Wen-na.Synthesis and Characterization of Dehydroabietylamine Schiff Bases and Copper(Ⅱ) Complexes[J].Chemical Research,2006,17(4):21-23. |
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| Authors: | CUI Guo-you MO Bing-rong CHEN Wen-na |
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| Abstract: | The four substitutedsalicylaldehydes: 5-bromosalicylaldehyde,5-chlorosalicylaldehyde,5-nitrosalicylaldehyde,3,5-dinitrosalicylaldehyde were synthesizedfrom salicylaldehyde.Dehydroabieticacid was isolated and purified from disproportionated rosin,then was converted into dehydroabietic chloride.Degrading-dehydroabietylamine was obtained by Curtius rearrangement.The five Schiffbases and their copper(Ⅱ) complexes were synthesized and identified by elemental analysis,~()IR and ~(1)H NMR. |
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| Keywords: | degrading-dehydroabietylamine salicylaldehyde Schiff base copper complexes |
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