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一种两性三元共聚物的合成
引用本文:崔文娟,庄玉伟,王颖,赵根锁,张国宝.一种两性三元共聚物的合成[J].化学研究,2010,21(3):39-41.
作者姓名:崔文娟  庄玉伟  王颖  赵根锁  张国宝
作者单位:1. 河南工业大学,化学化工学院,河南,郑州,450001
2. 河南省分析测试中心,河南,郑州,450002
摘    要:选用聚乙二醇二丙烯酸酯(PEGDA)为扩链剂,以丙烯酰胺(AM)、2-甲基-2-丙烯酰胺基丙磺酸(AMPS)、甲基丙烯酰氧乙基三甲基氯化铵(DMC)为主单体,采用水溶液聚合方法合成了两性三元共聚物AM/AMPS/DMC;测定了共聚物的性能,并利用红外光谱研究了其分子结构.结果表明,所合成的共聚物具有良好的耐酸和高温稳定性,以及高抗剪切率.

关 键 词:丙烯酰胺  2-甲基-2-丙烯酰胺基丙磺酸  甲基丙烯酰氧乙基三甲基氯化铵  两性三元共聚物  合成

Synthesis of an Amphiprotic Terpolymer
CUI Wen-juan,ZHUANG Yu-wei,WANG Ying,ZHAO Gen-suo,ZHANG Guo-bao.Synthesis of an Amphiprotic Terpolymer[J].Chemical Research,2010,21(3):39-41.
Authors:CUI Wen-juan  ZHUANG Yu-wei  WANG Ying  ZHAO Gen-suo  ZHANG Guo-bao
Institution:1.School of Chemistry,Henan University of Technology,Zhengzhou 450001,Henan,China;2.Henan Analysis and Testing Center,Zhengzhou 450002,Henan,China)
Abstract:An amphiprotic copolymer was synthesized via aqueous solution polymerization of acrylamide(AM),2-acryamido-2-methylpropane sulfate acid(AMPS),and methacrylatoethyl trimethyl ammonium chloride(DMC) in the presence of polyethylene glycol diacrylate(PEGDA) as the chain extender.The properties of the terpolymer were examined,and its molecular structure was analyzed by means of infrared spectrometry.Results indicate that the synthetic terpolymer has high viscosity,good thermal stability,and good shearing resistance.
Keywords:acrylamide  2-acryamido-2-methylpropane sulfate acid  methacrylatoethyl trimethyl ammonium chloride  amphiprotic copolymer  synthesis
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