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二硫二磺酸掺杂聚苯胺电化学性能的研究
引用本文:唐晓辉,李永舫,方世璧.二硫二磺酸掺杂聚苯胺电化学性能的研究[J].物理化学学报,1998,14(3):214-218.
作者姓名:唐晓辉  李永舫  方世璧
作者单位:Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080
摘    要:用聚有机二硫化物与聚苯质共混,是提高聚苯胺的电化学性能的有效方法之一.以二硫二磺酸为掺杂剂掺杂的聚苯胺,可明显地改善聚苯胺的电化学活性,使聚苯胶与掺杂剂中的-S-S-在相同的区域内共同参与氧化还原反应,提高了聚苯胺的电容量和充放电循环性.

关 键 词:聚苯胺  二硫二磺酸  电化学  二次电池  
收稿时间:1997-06-20
修稿时间:1997-09-23

Studies of Electrochemical Properties of PAn Doped with Disulfidedisulfonic Acid
Tang Xiaohui, Li Yongfang, Fang Shibi.Studies of Electrochemical Properties of PAn Doped with Disulfidedisulfonic Acid[J].Acta Physico-Chimica Sinica,1998,14(3):214-218.
Authors:Tang Xiaohui  Li Yongfang  Fang Shibi
Institution:Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080
Abstract:One method to improve efficiently polyaniline's electrochemical properties if the comixing of polyaniline with disulfide disulfonic acid. When doped with disulfidedisulfonic acid, polyaniline's electrochemical activity is greatly improved. The bondage-S-S-of the dopant coparticipates oxidation-reduction reaction with polyaniline in the same area, thus polyaniline's capacityand charge-discharge cyclibility are improved.
Keywords:Polyaniline  Disulfidedisulfonic acid  Electrochemical  Secondary battery
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