| 碱性介质中POTAS和PDTAS对铜的缓蚀作用 |
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| 引用本文： | 张秀娟,刘瑞泉,王献群.碱性介质中POTAS和PDTAS对铜的缓蚀作用[J].物理化学学报,2008,24(2):338-344. |
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| 作者姓名： | 张秀娟 刘瑞泉 王献群 |
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| 作者单位： | College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, P. R. China |
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| 摘 要： | 合成了两种吡唑啉酮衍生物POTAS 和PDTAS, 并采用失重法和电化学方法研究了这两种吡唑啉酮衍生物对铜在5%(w)NaHCO3水溶液中的缓蚀性能和吸附行为. 结果表明, 在5%NaHCO3水溶液中这两种化合物对铜均有较好的缓蚀作用, 缓蚀效率大小顺序为POTAS>PDTAS. 并且POTAS与PDTAS均为混合型缓蚀剂. 两种化合物在铜表面的吸附均为单层吸附, 属于物理吸附.
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| 关 键 词： | 缓蚀剂 铜 吡唑啉酮 NaHCO3 吸附行为 |
| 收稿时间： | 2007-08-09 |
| 修稿时间： | 2007-11-08 |
Inhibition Action and Adsorption Behavior of POTAS and PDTAS on Copper in Alkaline Medium |
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| ZHANG Xiu-Juan,LIU Rui-Quan,WANG Xian-Qun.Inhibition Action and Adsorption Behavior of POTAS and PDTAS on Copper in Alkaline Medium[J].Acta Physico-Chimica Sinica,2008,24(2):338-344. |
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| Authors: | ZHANG Xiu-Juan LIU Rui-Quan WANG Xian-Qun |
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| Institution: | College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, P. R. China |
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| Abstract: | Two pyrazolone compounds, POTAS and PDTAS, were synthesized and their inhibition action and adsorption behavior on copper in aqueous NaHCO3 (mass fraction 5%) solution were investigated by means of mass loss and electrochemical techniques. It was showed that the two compounds had good corrosion inhibition for copper in NaHCO3 solution. The inhibition efficiency of the two compounds was found to decrease as follows: POTAS>PDTAS. Both POTAS and PDTAS were mixed-type inhibitors. The results of experiment revealed that the adsorption on copper surface was monolayer adsorption. The adsorption processes were exothermic reaction and belong to physical absorption. |
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| Keywords: | Inhibitor Copper Pyrazolone NaHCO~ Adsorption behavior |
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