Kinetics of regioselective acetolysis of epichlorohydrin |
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Authors: | Rosilda Selvin Hsiu-Ling Hsu and Tze-Min Her |
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Institution: | (1) Department of Chemical and Materials Engineering, Lunghwa University of Science and Technology 300, Wan-shou Rd., Sec. 1, Kueishan, Taoyuan, Taiwan |
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Abstract: | The liquid phase acetolysis of epichlorohydrin (ECH) with acetic acid was studied over bentonite clay catalysts and was found
to be very active for the selective formation of 1-acetoxy-3-chloro-2-propanol. The reaction followed first order kinetics
with respect to epichlorohydrin and obeyed the Langmuir-Hinshelwood mechanism. |
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Keywords: | Acetolysis of epichlorohydrin bentonite kinetics clay catalysis |
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