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Kinetics of regioselective acetolysis of epichlorohydrin
Authors:Rosilda Selvin  Hsiu-Ling Hsu and Tze-Min Her
Institution:(1) Department of Chemical and Materials Engineering, Lunghwa University of Science and Technology 300, Wan-shou Rd., Sec. 1, Kueishan, Taoyuan, Taiwan
Abstract:The liquid phase acetolysis of epichlorohydrin (ECH) with acetic acid was studied over bentonite clay catalysts and was found to be very active for the selective formation of 1-acetoxy-3-chloro-2-propanol. The reaction followed first order kinetics with respect to epichlorohydrin and obeyed the Langmuir-Hinshelwood mechanism.
Keywords:Acetolysis of epichlorohydrin  bentonite  kinetics  clay catalysis
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