| 气相色谱-质谱法分析硫芥子气及相关化合物 |
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| 引用本文： | 李楠,张力量,周黎明,陈华康,谭有金,张汉才.气相色谱-质谱法分析硫芥子气及相关化合物[J].分析试验室,2003,22(1):86-89. |
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| 作者姓名： | 李楠 张力量 周黎明 陈华康 谭有金 张汉才 |
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| 作者单位： | 1. 中国人民解放军76349部队,广州,510650
2. 防化指挥工程学院,北京,102205 |
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| 摘 要： | 用气相色谱－质谱法对含硫芥子气类化合物进行了分析。探讨了长链芥子气的电子轰击电离的质谱规律，并对待测化合物的色谱保留数据进行了研究，在给定条件下，各种待测含硫芥子气在气相色谱柱中能有效的分离和鉴定。
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| 关 键 词： | 芥子气及相关化合物 气相色谱－质谱法 |
| 文章编号： | 1000-0720(2003)01-0086-04 |
The analysis of long chain sulphur mustard and related compounds by Gas chromatography-mass spectrometry |
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| LI Nan,ZHANG Li-liang,CHEN Hua-kang,TAN You-jin,ZHANG Han-cai.The analysis of long chain sulphur mustard and related compounds by Gas chromatography-mass spectrometry[J].Chinese Journal of Analysis Laboratory,2003,22(1):86-89. |
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| Authors: | LI Nan ZHANG Li-liang CHEN Hua-kang TAN You-jin ZHANG Han-cai |
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| Abstract: | The identification of sulfur-containing mustards was studied by gas chromatography-mass spectrometry. Under the applied conditions,the analysis species were separated effectively with the capillary columns coated with SE-54 stationary phases from the mixture solution. Electron-impact positive-ion mass spectra cleavage mechanisms of sulfur-mustards were discussed in detail. From the mass spectra of these compounds, general fragmentation pathways were derived. |
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| Keywords: | Sulfur-mustard Gas chromatography-mass spectrometry Cleavage mechanism Retention index |
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