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锌-硫氰酸盐-结晶紫体系共振散射法测定痕量锌
引用本文:翟好英,张银钏,王碧.锌-硫氰酸盐-结晶紫体系共振散射法测定痕量锌[J].分析试验室,2011,30(3):94-97.
作者姓名:翟好英  张银钏  王碧
作者单位:内江师范学院化学与生命科学学院,内江,641112
摘    要:在pH 5.0 NaAc-HAc介质和吐温80溶液中,研究了zn(SCN)42-与结晶紫形成的离子缔合微粒的共振散射光谱,考察了其各种影响因素和适宜的反应条件,确定了共振散射强度与Zn2+浓度的关系,建立了测定痕量zn(Ⅱ)的共振散射新方法.研究表明,在0.020~0.80μg/mL范围内,体系的共振散射强度△I与Zn...

关 键 词:  硫氰酸钾  结晶紫  共振散射

Resonance scattering determination of trace zinc with Zn~(2+)-thiocyanate-crystalline violet system
ZHAI Hao-ying,ZHANG Yin-Chuan,WANG Bi.Resonance scattering determination of trace zinc with Zn~(2+)-thiocyanate-crystalline violet system[J].Chinese Journal of Analysis Laboratory,2011,30(3):94-97.
Authors:ZHAI Hao-ying  ZHANG Yin-Chuan  WANG Bi
Institution:ZHAI Hao-ying,ZHANG Yin-Chuan and WANG Bi(Department of Chemistry and Life Science,Neijiang Normal University,Neijiang 641112)
Abstract:Resonance scattering(RS) spectra of Zn(SCN)42-with crystal violet were studied in pH 5.0 NaAc-HAc medium and Tween 80 solution.The affecting factors and the optimum conditions of the reaction were investigated.A new method for the determination of trace Zine based on the relationship between the resonance scattering intensity and the concentration of Zn2+ was established.The results showed that there was a good linear relationship between the resonance scattering intensity and Zn2+ concentration in the rang...
Keywords:Zinc  Potassium thiocyanate  Crystal Violet  Resonance scattering  
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