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Ion-exchange synthesis and improved photovoltaic performance of CdS/Ag2S heterostructures for inorganic-organic hybrid solar cells
Institution:1. School of Materials Science and Engineering, Nanjing University of Science and Technology, Nanjing 210094, China;2. Key Laboratory for Micro-Nano Energy Storage and Conversion Materials of Henan Province, Institute of Surface Micro and Nano Materials, Xuchang University, Xuchang 461000, China;1. School of Metallurgy and Materials Engineering, Chongqing University of Science and Technology, Chongqing, 401331, China;2. Chongqing Key Laboratory of Nano/Micro Composite Materials and Devices, Chongqing, 401331, China;1. Baku State University, Department of Chemistry, Z. Khalilov str. 23, AZ-1148 Baku, Azerbaijan;2. Institute of Physics, Azerbaijan National Academy of Sciences, H. Javid pr, 131, Baku AZ-1143, Azerbaijan;3. Institut für Technische Chemie, Leibniz Universität Hannover, Callinstrasse 5, D-30167 Hannover, Germany;4. Institut für Festkörperphysik, Leibniz Universität Hannover, Appelstrasse 2, D-30167 Hannover, Germany;1. Power Engineering Lab., Dep. of Electrical and Electronic Engineering, Kitami Institute of Technology, Koen-cho 165, Kitami, Hokkaido, 090-8507, Japan;2. Dep. of Mechanical Systems Engineering, National Institute of Technology, Asahikawa College, Shyunkodai 2-2-1-6, Asahikaw, Hokkaido, 071-8142, Japan;3. Technology Innovation Center, National Institute of Technology, Asahikawa College, Shyunkodai 2-2-1-6, Asahikaw, Hokkaido, 071-8142, Japan;1. Associate Professor, Department of Architectural Engineering, Yonsei University, Seoul, 03722, Republic of Korea;2. Ph.D. Candidate, Department of Architectural Engineering, Yonsei University, Seoul, 03722, Republic of Korea;3. Visiting Scholar, Division of Construction Engineering and Management, Purdue University, West Lafayette, IN 47906 & Research Professor, Postdoctoral Fellow, Department of Architectural Engineering, Yonsei University, Seoul, 03722, Republic of Korea;4. Ph.D. Student, Department of Architectural Engineering, Yonsei University, Seoul, 03722, Republic of Korea;1. Research Scholar, School of Electrical Engineering, VIT University, Vellore-632014, Tamil Nadu, India;2. Associate Professor, School of Electrical Engineering, VIT University, Vellore-632014, Tamil Nadu, India;1. Department of Electrical and Computer Engineering, Faculty of Science and Engineering, Kasetsart University, Chalermphrakiat Sakonnakhon Province Campus, Sakonnakhon 47000 Thailand;2. Department of Chemical Engineering, Faculty of Engineering, King Mongkut''s University of Technology Thonburi, Bangmod, Bangkok 10140 Thailand
Abstract:A facile ultrasound-assisted ion exchange route was developed for the synthesis of CdS/Ag2S heterojunctions by ion exchange between the nanostructured CdS film and Ag(NH3)2]+ under ultrasonication. The CdS/Ag2S heterojunction film was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), UV-vis DRS spectroscopy, photoelectrochemical measurements, and the transient photovoltage (TPV) technique. CdSsingle bondAg2S heterojunctions exhibit a dense morphology, enhanced visible light absorption and stronger photocurrent response than the pure CdS films. Poly(3-hexylthiophene) (P3HT) was then spin coated into the CdS/Ag2S framework. Hybrid solar cells constructed with FTO/CdS/Ag2S/P3HT/Au display relatively higher power conversion efficiency than FTO/CdS/P3HT/Au.
Keywords:Composites  Thin films  Chemical synthesis  Photovoltaic
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