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Pressure‐induced polymerization of tetraethylene glycol dimethacrylate
Authors:Kamil Kaminski  Marian Paluch  R Wrzalik  Jerzy Ziolo  Radoslav Bogoslovov  C Michael Roland
Institution:1. Institute of Physics, Silesian University, Uniwersytecka 4, 40‐007 Katowice, Poland;2. Chemistry Division, Code 6120, Naval Research Laboratory, Washington, DC 20375‐5342
Abstract:The polymerization and crosslinking of tetraethylene glycol dimethacrylate were induced by high pressure. The product was analyzed by both swelling experiments and broadband dielectric spectroscopy to determine the structure, with IR measurements used to follow the extent of reaction and its temperature dependence. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 3795–3801, 2008
Keywords:acrylates  crosslinking  degree of polymerization (DP)  dielectric properties  molecular dynamics  polymerization  pressure  swelling
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