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| 丙烯酸铈(Ⅲ)-丙烯酸丁酯对明胶的接枝共聚鞣制 | |
| 引用本文： | 邵双喜,刘力,王金明,魏晋,聂晓勤.丙烯酸铈(Ⅲ)-丙烯酸丁酯对明胶的接枝共聚鞣制[J].合成化学,2000,8(6):537-540. |
| 作者姓名： | 邵双喜 刘力 王金明 魏晋 聂晓勤 |
| 作者单位： | 1. 中国科学院成都有机化学研究所,成都,610041 2. 南京浦口橡胶总厂 3. 解放军成都医学专科学校药剂教研室,成都,610083 |
| 摘 要： | 以（ＮＨ４）２Ｓ２Ｏ８－ＮａＨＳＯ３作引发剂，用丙烯酸丁酯和丙烯酸铈（Ⅲ）对明胶进行乳液接枝共聚鞣制。考察了乳化剂种类及用量、介质ＰＨ值，乳液固含量和离子浓度等因子对反应及乳液稳定性的影响，通过对合成聚合物与明胶结全形式的研究，探讨了接枝共聚鞣制的机理。 |
| 关 键 词： | 丙烯酸铈 接枝共聚鞣制 明胶 丙烯酸丁酯 改性 |
| 修稿时间： | 2000年6月6日 |
The Graft Copolymeric Tanning of Gelatin with Cerous Triacrylate and Butyl Acrylate |
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| Shao,Shuang-Xi Liu,Li Wang,Jin-Ming Wei,Jin.The Graft Copolymeric Tanning of Gelatin with Cerous Triacrylate and Butyl Acrylate[J].Chinese Journal of Synthetic Chemistry,2000,8(6):537-540. | |
| Authors: | Shao Shuang-Xi Liu Li Wang Jin-Ming Wei Jin |
| Abstract: | The graft copolymeric tanning of gelatin with cerous triacrylate and butyl acrylate using (NH_4)_2S_2O_8/NaHSO_3 redox system as an initiator in emulsion polymerization was performed. The various factors affected the stability of the emulsion such as pH, emulsifer, and content of cerous etc. were investigated. The graft copolymeric tanning mechanism was suggested and discussed as well. |
| Keywords: | Cerous triacrylate complex Gelatin Graft copolymeric tanning Butyl acrylate Mechanisml |
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