| N－取代硫代磷酰胺二乙酯合成新方法的研究 |
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| 引用本文： | 郭佃顺,黄汝骐,高蓉华,吴志广.N－取代硫代磷酰胺二乙酯合成新方法的研究[J].合成化学,1994(2). |
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| 作者姓名： | 郭佃顺 黄汝骐 高蓉华 吴志广 |
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| 作者单位： | 山东师范大学化学系 |
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| 摘 要： | 以ＰＥＧ作相转移催化剂，在无机碱（Ｋ＿２ＣＯ＿３或Ｎａ＿２ＣＯ＿３）存在下，用乙基氯化物（Ｏ，Ｏ－二乙基硫代磷酰氯）与不同的胺反应，合成了六种Ｎ－取代硫代磷酰胺二乙酯，其结构经ＩＲ、ＮＭＲ和元素分析证实。
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| 关 键 词： | N－取代硫代磷酰胺二乙酯，相转移催化，合成 |
Study on the New Method for Synthesis ofN-Substituted-O , O-diethylphosphoramidothioates |
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| Guo,Dian-Shun,Huang,Ru-Qi,Gao,Rong-Hua,Wu,Zhi-Guang.Study on the New Method for Synthesis ofN-Substituted-O , O-diethylphosphoramidothioates[J].Chinese Journal of Synthetic Chemistry,1994(2). |
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| Authors: | Guo Dian-Shun Huang Ru-Qi Gao Rong-Hua Wu Zhi-Guang |
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| Abstract: | N-Substitute-O, O-diethylphosphoramidothioates(I) were prepered by treating O , O-di-ethylphcophorochloridothioate with different amines in the preesence of anhydrous potassium carbonatewith polyethylene glycol as phase transfer catalyst. The chemical structures of the preducts were con-firmed by elementary analysis, IR and NMR spectra. |
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| Keywords: | N-Subetituted-O O-diethylphosphoramidothioate Phase transfer catalysis Synthe-sis |
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