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电动分离统一理论
引用本文:陈义.电动分离统一理论[J].色谱,2020,38(10):1211-1216.
作者姓名:陈义
作者单位:淮阴工学院, 江苏 淮阴 223001; 中国科学院化学研究所, 中国科学院活体分析化学重点实验室, 北京 100190; 中国科学院大学, 北京 100049; 北京分子科学国家实验室, 北京 100190
基金项目:国家自然科学基金项目(21727809);中国科学院项目(QYZDJ-SSW-SLH034)
摘    要:在真空、气相和液相中实施线性电动分离,创造出了质谱、离子淌度谱、电泳和毛细管电泳等,但它们却未成体系,各自发展,各有理论,互不相关。该文从牛顿力学第二定律出发结合静电学理论,推导出了它们的统一运动方程,并由此推演出并简要讨论了上述各法自己的通用运动子方程和测量模式。这些方程不仅有利于系统化这些现存方法,也可用于推导和发现新型电动分离模式。

关 键 词:质谱  离子淌度谱  电泳  毛细管电泳  统一理论  
收稿时间:2020-07-31

Unified theory of electroseparations
CHEN Yi.Unified theory of electroseparations[J].Chinese Journal of Chromatography,2020,38(10):1211-1216.
Authors:CHEN Yi
Institution:Huaiyin Institute of Technology, Huaiyin 223001, China; CAS Key Laboratory of Analytical Chemistry for Living Biosystems, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China; University of Chinese Academy of Sciences, Beijing 100049, China; Beijing National Center for Molecular Sciences, Beijing 100190, China
Abstract:Linear electroseparations in vacuum, gas phase and liquid phase have created mass spectrometry, ion mobility spectrometry, electrophoresis and capillary electrophoresis. However, they have not systematized yet, developing independently, with their own theory, not related to each other. In this paper, unified motion equations were derived from the second law of Newtonian mechanics combined with electrostatic theory. From them, the general sub-equations of motion and measurement modes of all the above-mentioned methods were deduced and discussed briefly. These equations are not only helpful to systematize these existing methods but also are usable to deduce and discover novel electro-separation modes.
Keywords:mass spectrometry (MS)  ion mobility spectrometry (IMS)  electrophoresis  capillary electrophoresis (CE)  unified theory  
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