毛细管电泳分析中手性化合物的定性检测

毛细管电泳（CE）作为一种新型分离分析技术，具有分离效率高、分析速度快、样品用量少、分离模式灵活多样等众多优势，在手性物质分离等领域应用广泛。在以往的工作中，手性化合物的CE分离模式、手性拆分剂选择及提高分离度等研究已作了详尽报道，而成功分离后的手性物质定性、对映体出峰顺序确认等问题也至关重要。该文以CE手性化合物分离分析中是否依赖标准品分类，及其定性检测方法进行了总结。

Qualitative determination of chiral compounds using capillary electrophoresis

As a well-established analytical separation technique, capillary electrophoresis (CE) is widely used in the separation of chiral substances because of its numerous advantages such as high separation efficiency, short analysis time, small sample dosage, and flexible separation modes. In the previous studies, the CE separation mode, selection of the chiral dispersant and improvement of the separation degree of chiral compounds have been reported in detail. Moreover, it is important to determine the quality of chiral substances and confirm the order of enantiomer peaks after successful separation. This paper summarizes the qualitative detection methods for CE chiral compounds, based on whether the separation analysis of chiral compounds depends on the classification of standard materials.