| 有机金属化合物的振动光谱I:环戊二烯夹心化合物的力常数计算 |
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| 引用本文： | 冯艳,刘举正,赵文运,张刚,梁映秋.有机金属化合物的振动光谱I:环戊二烯夹心化合物的力常数计算[J].化学学报,1988,46(2):131-136. |
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| 作者姓名： | 冯艳 刘举正 赵文运 张刚 梁映秋 |
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| 作者单位： | 吉林大学理论化学研究所 |
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| 摘 要： | 测定了过渡金属环戊二烯夹心化合物的红外与激光拉曼光谱,在此基础上,用G-F矩阵法计算了这类化合物的力常数.讨论了环戊二烯与金属间化学键的性质.
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| 关 键 词： | 计算 环戊二烯P 光谱分析 有机金属化合物 金属茂络合物 振动谱 力常数 |
The vibrational spectra of organometallic compounds I: On the calculation of force constant for metallocene |
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| FENG YAN,LIU JUZHENG,ZHAO WENYUN,ZHANG GANG,LIANG YINGQIU.The vibrational spectra of organometallic compounds I: On the calculation of force constant for metallocene[J].Acta Chimica Sinica,1988,46(2):131-136. |
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| Authors: | FENG YAN LIU JUZHENG ZHAO WENYUN ZHANG GANG LIANG YINGQIU |
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| Abstract: | On the basis of FT-IR and laser Raman spectra of (h5-Cp)2M (Cp = C5H5; M = Mn, Fe, Ru), the force constants of the given compounds have been calculated by a G-F matrix program and the nature of the Cp-M chem. bond has been discussed. |
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| Keywords: | CALCULATION CYCLOPENTADIENE P SPECTROGRAPHIC ANALYSIS ORGANOMETALLIC COMPOUNDS METALLOCENES VIBRATIONAL SPECTRA FORCE CONSTANT |
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