| 硫杂杯[4]芳烃氧化膦衍生物的合成与晶体结构 |
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| 引用本文： | 马淑兰,郭倩玲,朱文祥,赵明新,张静,刘迎春.硫杂杯[4]芳烃氧化膦衍生物的合成与晶体结构[J].化学学报,2005,63(6):519-524. |
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| 作者姓名： | 马淑兰 郭倩玲 朱文祥 赵明新 张静 刘迎春 |
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| 作者单位： | 北京师范大学化学系,北京,100875;北京化工大学化学工程学院,北京,100029 |
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| 基金项目： | 北京市自然科学基金(No.2022011)，北京师范大学青年基金(No.10770005)资助项目. |
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| 摘 要： | 合成了部分取代的硫杂杯4]芳烃氧化膦衍生物, 二(亚甲基二苯基氧化膦)对叔丁基硫杂杯4]芳烃(化合物1), 培养了化合物的单晶, 用Smart 1000 CCD衍射仪测定了其晶体结构. 结果表明, 1的组成为: C66H70O6P2S4•2CH3OH, 属三斜晶系, P1空间群, 晶胞参数a＝1.3453(6) nm, b＝1.5289(7) nm, c＝1.7893(9) nm; α＝75.707(9)°, β＝69.131(8)°, γ＝79.734(9)°, Z＝2; V＝3.316(3) nm3, d＝1.215 g/cm3, F(000)＝1288, μ (Mo Kα)＝0.244 mm－1, R1＝0.0625, wR2＝0.1372. 杯芳烃分子采取了锥式构象.
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| 关 键 词： | 硫杂杯[4]芳烃 氧化膦衍生物 晶体结构 |
| 收稿时间： | 2004-8-23 |
| 修稿时间： | 2004-11-28 |
Synthesis and Crystal Structure of Thiacalix[4]arene Substituted by Two Diphenylphosphinylmethoxy Groups [OCH2P(O)Ph2] |
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| MA Shu-Lan,GUO Qian-Ling,ZHU Wen-Xiang,ZHAO Ming-Xin,ZHANG Jing,LIU Ying-Chun.Synthesis and Crystal Structure of Thiacalix[4]arene Substituted by Two Diphenylphosphinylmethoxy Groups [OCH2P(O)Ph2][J].Acta Chimica Sinica,2005,63(6):519-524. |
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| Authors: | MA Shu-Lan GUO Qian-Ling ZHU Wen-Xiang ZHAO Ming-Xin ZHANG Jing LIU Ying-Chun |
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| Institution: | ( Department of Chemistry, Beijing Normal University, Beijing 100875)( College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029) |
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| Abstract: | The lower-rim doubly substituted thiacalixarene, 5,11,17,23-tetra-tert-butyl-25,27-bis(diphenylphosphinylmethoxy)thiacalix4]arene (compound 1), has been synthesized. The crystal structure of the compound was determined by X-ray diffraction. The result shows that the composition of compound 1 is C66H70O6P2S4•2CH3OH. It belongs to triclinic crystal system, space group P1, with a＝1.3453(6) nm, b＝1.5289(7), c＝1.7893(9) nm, α＝75.707(9)°, β＝69.131(8)°, γ＝79.734(9)°, Z＝2, V＝3.316(3) nm3, d＝1.215 g/cm3, F(000)＝1288, μ(Mo Kα)＝0.244 mm－1, R1＝0.0625, wR2＝0.1372. The compound adopts a cone conformation. |
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| Keywords: | thiacalix[4]arene phosphinoxide crystal structure |
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