| 苯乙烯间规聚合催化剂进展 |
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| 引用本文： | 沈志刚,林尚安.苯乙烯间规聚合催化剂进展[J].高分子通报,2002(3):45-51,68. |
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| 作者姓名： | 沈志刚 林尚安 |
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| 作者单位： | 1. 中山大学高分子研究所,广州,510275上海石油化工研究院,上海,201208
2. 中山大学高分子研究所,广州,510275 |
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| 基金项目： | 国家科技部“九五”攻关资助课题 (批准号 :96 A1 2 0 2 0 5 ) |
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| 摘 要： | 综述了苯乙烯间规聚合主催化剂的研究和开发状况。主要介绍茂、茚、多元稠合环，氟和非茂钛等较高活性催化剂的催化特性，从取代基的电子效应和空间效应以及活性种稳定性等方面阐述了不同催化剂的聚合活性差异。
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| 关 键 词： | 苯乙烯 间规聚合 催化剂 茂钛 间规聚苯乙烯 多元稠合环肽 茚钛 |
Development of Catalysts for Syndiotactic Polymerization of Styrene |
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| SHEN Zhi\|gang\\{,\},LIN Shang\|an\.Development of Catalysts for Syndiotactic Polymerization of Styrene[J].Polymer Bulletin,2002(3):45-51,68. |
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| Authors: | SHEN Zhi\|gang\\{ \} LIN Shang\|an\ |
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| Institution: | SHEN Zhi\|gang\+\{1,2\},LIN Shang\|an\+1 |
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| Abstract: | The current development of catalysts used for syndiotactic polymerization of styrene has been reviewed. This paper focused on some high active catalysts including cyclopentadienyltitanium, indenyltitanium, fused\|ring titanium, fluorinated\|titanium and non\|metallocene titanium. The different activity of catalysts was explained with the electron and steric effect of substitunents and the stability of active species. |
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| Keywords: | Syndiotactic polystyrene Catalysts Metallocene\|titanium Review |
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