Gold-catalyzed Intermolecular Oxidation of Phenylacetylene and Allylic Sulfides: an Efficient and Practical Synthesis of α-Phenylthio Ketone |
| |
| Authors: | ZHENG Renhua HUANG Qing GUOHaichang HUANGYidie JIANG Huajiang |
| |
| Institution: | 1. School of Pharmaceutical and Chemical Engineering, Taizhou University, Taizhou 318000, P. R. China;
2. College of Pharmaceutical Science, Zhejiang University of Technology, Hangzhou 310014, P. R. China |
| |
| Abstract: | An efficient and practical synthesis of α-phenylthio ketone through gold-catalyzed intermolecular oxidation of phenylacetylene and substituted aryl(benzyl) allylic sulfides was developed. The reaction scope is fairly good with substituted aryl(benzyl) allylic sulfides, tolerating various functional groups, and the reaction affords the yields of 63%—85%. |
| |
| Keywords: | Gold-catalyst α-Phenylthio ketone Oxidation Phenylacetylene |
|
| 点击此处可从《高等学校化学研究》浏览原始摘要信息 |
| 点击此处可从《高等学校化学研究》下载免费的PDF全文 |
