| 毛细管电泳柱端盘状电极安培检测区带展宽的定量分析 |
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| 引用本文： | 傅崇岗,王安宝.毛细管电泳柱端盘状电极安培检测区带展宽的定量分析[J].分析化学,1998,26(9):1085-1088. |
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| 作者姓名： | 傅崇岗 王安宝 |
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| 作者单位： | 华东师范大学化学系!上海200062 |
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| 基金项目： | 中国科学院长春应用化学研究所电分析化学开放研究实验室基金资助课题。 |
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| 摘 要： | 从理论上分析了影响毛细管电泳法端盘状电极安培区检测区带展宽的诸因素，给出了区带展宽的模拟公式，通过实验考察了进样量，分离电压，检测器体体积对区带展宽的影响并验证了模拟公式。
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| 关 键 词： | 毛细管电泳 安培检测 区带展宽 仪器参数 |
Quantitative Analysis of Zone Broadening in Capillary Electrophoresis - Amperometric Detection at Disk-shaped Electrode |
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| Fu Chonggang,Wang Anbao,Song Linan,Fang Yuzhi.Quantitative Analysis of Zone Broadening in Capillary Electrophoresis - Amperometric Detection at Disk-shaped Electrode[J].Chinese Journal of Analytical Chemistry,1998,26(9):1085-1088. |
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| Authors: | Fu Chonggang Wang Anbao Song Linan Fang Yuzhi |
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| Abstract: | The factors affecting zone broadening in capillary electrophoresis - amperometric detection (CE/ AD) at a disk-shaped electrode were theoretically analysed, and a model equation about it was given. The effect of injection time of sample, separation voltage and dead volume of the detector on zone broadening was experimentally examined, and the model equation accounting for zone broadening was verified. |
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| Keywords: | Capillary electrophoresis amperometric detection zone broadening |
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