| 六氟磷酸二(4,4'-二甲基-2,2'-联吡啶)·(2,2'-联吡啶-4,4'-二羧酸)合钌(Ⅱ)的二维核磁共振 |
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| 引用本文： | 王鹏,袁艺,景晓燕,朱果逸.六氟磷酸二(4,4'-二甲基-2,2'-联吡啶)·(2,2'-联吡啶-4,4'-二羧酸)合钌(Ⅱ)的二维核磁共振[J].分析化学,1999,27(11):1337-1340. |
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| 作者姓名： | 王鹏 袁艺 景晓燕 朱果逸 |
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| 作者单位： | 1. 中国科学院长春应用化学研究所,国家电化学和光谱研究分析中心,长春,130022
2. 哈尔滨工程大学化学工程系,哈尔滨,150001 |
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| 基金项目： | 国家科技攻关项目;96-A23-03-01; |
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| 摘 要： | 用1H NMR和13C NMR谱研究了新型电化学发光探针六氟磷酸二(4,4'-二甲基-2,2'-联吡啶)·(4,4'-二羧酸-2,2'-联吡啶)合钌(Ⅱ)的立体结构,通过1H-1H COSY、13C-1H HETCOR谱对其氢谱和碳谱中的各谱峰进行了归属,并给出了氢谱和碳谱峰的化学位移值.
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| 关 键 词： | 络合物 六氟磷酸二(4 4'-二甲基-2 2'-联吡啶)·(4 4'-二羧酸-2 2'-联吡啶)合钌(Ⅱ) 二维核磁共振 |
| 修稿时间： | 1998年10月30日 |
Two Dimensional Nuclear Magnetic Resonance Analysis of Ruthenium- ( 4,4'- dimethyl-2,2'-bipyridine ) 2 ( 2,2'-bipyridine-4,4'-dicarboxylic Acid ) ( PF6) 2 |
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| Wang Peng,Yuan Yi,Jing Xiaoyan,Zhu Guoyi.Two Dimensional Nuclear Magnetic Resonance Analysis of Ruthenium- ( 4,4'- dimethyl-2,2'-bipyridine ) 2 ( 2,2'-bipyridine-4,4'-dicarboxylic Acid ) ( PF6) 2[J].Chinese Journal of Analytical Chemistry,1999,27(11):1337-1340. |
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| Authors: | Wang Peng Yuan Yi Jing Xiaoyan Zhu Guoyi |
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| Abstract: | The 1H and 13C NMR spectra are reported for Ru(4,4'-dimethyl-2, 2'-bipyridine)2 (2,2'-bipyridine-4,4'-dicarboxylic acid) (PF6)2 that can be used as a new electrochemiluminescent probe in immunoasssay and nucleic acid hybridization assay. Because of the effect of Ru atom on ligands and complex steric configuration, it is difficult to attribute spectra of the title molecular. By using 2D 1 H-1H COSY and 1 H-13C HETCOR method, the proton and 13C NMR spectra are assigned completely, which provides a satisfactory method to quantitative and qualitative analysis of the title moleculer in the further study. |
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| Keywords: | Electrochemiluminescent probe ruthenium (4 4'-dimethyl-2 2'-bipyridine)2 (2 2'-bipyridine-4 4'-dicarboxylic acid) two dimensional nuclear magQetic resonance spectroscopy |
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