| 水杨醛缩2-芴胺席夫碱的合成、晶体结构及生物活性 |
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| 引用本文： | 刘红霞,张业明,朱雅兰,刘桥阳,吴风林.水杨醛缩2-芴胺席夫碱的合成、晶体结构及生物活性[J].化学研究与应用,2009,21(11). |
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| 作者姓名： | 刘红霞 张业明 朱雅兰 刘桥阳 吴风林 |
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| 作者单位： | 黄石理工学院,环境科学与工程学院,湖北,黄石,435003 |
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| 基金项目： | 黄石理工学院科研项目 |
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| 摘 要： | 芴在煤焦油中的含量为1%～2%,全国每年可从中提取1.4万吨芴.芴是一种带有荧光的片状化合物,作为一种新型的发光材料主要用于制备芴基金属化合物、有机光导体、树脂、染料、Ziegler-Natta催化剂的给电子体等.
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| 关 键 词： | 水杨醛 2-芴胺 席夫碱 晶体结构 生物活性 |
Synthesis, crystal structure and biological activity of salicylaldehyde-fluoreylamine Schiff base |
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| Abstract: | The synthesis of a new Schiff base(salicylaldehyde-fluorenylamine) with fluorene was reported. The molecular structure was characterized by IR,~1H NMR,MS and elementary analysis. The crystal structure was determined by X-ray diffraction method. The crystal belongs to monoclinic,space group P2(1)/c with a = 1. 60170(6)nm,b = 0. 82261(8)nm,c = 1. 11693 (2)nm,β = 96.671(7)°,V= 1.4617(2) nm~3,Z = 4,D_c = 1. 297g/cm~3,μ(MoKα) = 0.080mm~(-1),F(000) - 600,R_1, = 0. 0857 , WR_2 = 0. 1989. The biological activity test indicated that it was an effective bactericide on bacillus such as Staphylococcus aureus, Bacillus thuring Iensis and Bacillus subtilis. |
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| Keywords: | salicylaldehyde 2-fluoreylamine Schiff base crystal structure biological activity |
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