| 新型酯键型鹅去氧胆酸分子钳的设计合成 |
| |
| 引用本文： | 赵志刚,张佩玉,杨祖幸,陈淑华.新型酯键型鹅去氧胆酸分子钳的设计合成[J].有机化学,2005,25(6):679-683. |
| |
| 作者姓名： | 赵志刚 张佩玉 杨祖幸 陈淑华 |
| |
| 作者单位： | 四川大学化学学院,成都,610064 |
| |
| 摘 要： | 以鹅去氧胆酸为隔离基、芳香族化合物为手臂设计合成了一类新型的分子钳, 其结构经1H NMR, IR, MS和元素分析确证, 并且考察了其对D/L-氨基酸甲酯的对映选择性识别性能. 初步的结果表明, 这类手性分子钳对D-氨基酸甲酯有较好的识别性能.
|
| 关 键 词： | 鹅去氧胆酸 分子钳 合成 |
| 收稿时间： | 2004-8-5 |
| 修稿时间： | 2004年8月5日 |
Design and Synthesis of Novel Ester-type Molecular Tweezers Derived from Chenodeoxycholic Acid |
| |
| ZHAO Zhi-Gang,ZHANG,Pei-Yu,YANG Zu-Xing,CHEN Shu-Hua.Design and Synthesis of Novel Ester-type Molecular Tweezers Derived from Chenodeoxycholic Acid[J].Chinese Journal of Organic Chemistry,2005,25(6):679-683. |
| |
| Authors: | ZHAO Zhi-Gang ZHANG Pei-Yu YANG Zu-Xing CHEN Shu-Hua |
| |
| Institution: | (Faculty of Chemistry, Sichuan University, Chengdu 610064) |
| |
| Abstract: | A novel type of chiral molecular tweezers has been designed and synthesized by using chenode- oxycholic acid as spacer and aromatic compounds as arm. Their structures were confirmed by 1H NMR, IR, MS spectra and elemental analysis. Their recognition properties for methyl esters of amino acids were inves- tigated. The preliminary results indicate that these chiral molecular tweezers are favorable for complexation with D-amino acid methyl esters. |
| |
| Keywords: | chenodeoxycholic acid molecular tweezer synthesis |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《有机化学》浏览原始摘要信息 |
| 点击此处可从《有机化学》下载免费的PDF全文 |
|
