| 卟啉-salen化合物的合成及谱学性质研究 |
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| 引用本文： | 赵小菁,阮文娟,朱志昂,金黎明,范圣第.卟啉-salen化合物的合成及谱学性质研究[J].有机化学,2006,26(8):1087-1092. |
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| 作者姓名： | 赵小菁 阮文娟 朱志昂 金黎明 范圣第 |
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| 作者单位： | 1. 大连民族学院生物工程系,大连,116600
2. 南开大学化学系,天津,300071 |
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| 基金项目： | 国家自然科学基金(Nos.20472013,20303009)，辽宁省教育厅(No.05L060)资助项目. |
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| 摘 要： | 合成了三种含羟基的salen化合物: salen-OH, Cl-salen-OH和t-Bu-salen-OH, 并用后两种羟基salen与5,10,15-三苯基-20-对羟基苯基卟啉(HPTPP)以烷烃链O(CH)6O及O(CH)10O]相连合成四种卟啉-salen化合物: HPSC6 (1), HPSC10 (2), HPt-BuSC6 (3), HPt-BuSC10 (4)及其金属锌(II)化合物: ZnPSC6 (Zn-1), ZnPSC10 (Zn-2), ZnPt-BuSC6 (Zn-3), ZnPt-BuSC10 (Zn-4). 用元素分析、核磁共振、红外光谱、紫外-可见光谱等手段对其组成的结构进行表征, 并对其谱学性质进行了研究.
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| 关 键 词： | 卟啉-salen化合物 合成 光谱性质 |
| 收稿时间： | 09 20 2005 12:00AM |
| 修稿时间： | 02 28 2006 12:00AM |
Study on Synthesis and Spectral Properties of Porphyrin-salen Compounds |
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| ZHAO, Xiao-Jing,RUAN, Wen-Juan,ZHU, Zhi-Ang,JIN, Li-Ming,FAN, Sheng-Di.Study on Synthesis and Spectral Properties of Porphyrin-salen Compounds[J].Chinese Journal of Organic Chemistry,2006,26(8):1087-1092. |
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| Authors: | ZHAO Xiao-Jing RUAN Wen-Juan ZHU Zhi-Ang JIN Li-Ming FAN Sheng-Di |
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| Institution: | 1. Department of Biochemical Engineering, Dalian Nationalities University, Dalian 116600;2. Department of Chemistry, Nankai University, Tianjin 300071 |
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| Abstract: | Three salen compounds: salen-OH, Cl-salen-OH and t-Bu-salen-OH with hydroxyl group were synthesized. By salen-OH and t-Bu-salen-OH with 5,10,15-triphenyl-20-mesohydroxylphenylporphyrin (HPTPP) as a starting material, respectively, a series of novel porphyrin-salen compounds: HPC6S (1), HPC10S (2), HPC6S' (3) and HPC10S' (4) and their corresponding zinc(II) porphyrin-salen complexes: ZnPC6S (Zn-1), ZnPC10S (Zn-2), ZnPC6S' (Zn-3), ZnPC10S' (Zn-4) were synthesized and characterized by elemental analysis, FTIR, 1H NMR and UV-Vis spectra, where P denotes porphyrin, S means salen and S' indicates t-Bu-salen. |
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| Keywords: | porphyrin-salen compound synthesis spectral property |
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