Efficiency and mechanism of new poly(acryl-phenylamidrazone phenylhydrazide) chelating fiber for adsorbing trace Ga, In, Bi, V and Ti from solution

A new po1y(acrylphenylamidrazone phenylhydrazide) chelating fiber is synthesized from polyacrylonitrile fiber and used for preconcentration and separation of trace Ga(III), In(III), Bi(III), V(V) and Ti(IV) from solution (5–50 ng ml^?1 Ti(IV) or V(V) and 50–500 ng ml^?1 Ga(III), In (III) or Bi(III) in 1000–100 ml of solution can be enriched quantitatively by 0.15 g of fiber at a 4 ml min^?1 flow rate in the pH range 5–7 with recoveries >95%). These ions can be desorbed quantitatively with 20 ml of 4 M hydrochloric acid at 2 ml min^?1 from the fiber column. When the fiber which had been treated with concentrated hydrochloric acid and washed with distilled water until neutral was reused eight times, the recoveries of the above ions by enrichment were still >95%. Two-hundred-fold to 10 000-fold excesses of Cu(II), Zn(II), Ca(II), Mn(II), Cr(III), Fe(III), Ba(II) and Al(III) caused little interference in the determination of these ions by inductively coupled plasma-atomic emission spectrometers (ICP-AES). The relative standard deviations for enrichment and determination of 50 ng ml^?1 Ga, In or Bi and 10 ng ml^?1 V or Ti are in the range 1.2–2.7%. The contents of these ions in real solution samples determined by this method were in agreement with the certified values of the samples with average errors <3.7%.