| Fe1/2Al1/2PO4催化1,2-二氯丙烷脱氯氧化制备环氧丙烷 |
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| 引用本文： | 钟顺和,顾修君,李兴波,肖秀芬.Fe1/2Al1/2PO4催化1,2-二氯丙烷脱氯氧化制备环氧丙烷[J].应用化学,2001,18(1):0-0. |
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| 作者姓名： | 钟顺和 顾修君 李兴波 肖秀芬 |
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| 作者单位： | 天津大学化工学院 |
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| 摘 要： | Fe1/2Al1/2PO4催化1;2-二氯丙烷脱氯氧化制备环氧丙烷
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| 关 键 词： | Fe1/2Al1/2PO4催化1 2-二氯丙烷脱氯氧化制备环氧丙烷 |
| 收稿时间： | 2009-06-29 |
| 修稿时间： | 2009-06-29 |
Fe_(1/2) Al_(1/2)PO_4 Catalyst for Preparation of Propylene Oxide from 1,2-Dichloropropane |
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| ZHONG Shun He ,GU Xiu Jun,LI Xing Bo,XIAO Xiu Fen.Fe_(1/2) Al_(1/2)PO_4 Catalyst for Preparation of Propylene Oxide from 1,2-Dichloropropane[J].Chinese Journal of Applied Chemistry,2001,18(1):0-0. |
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| Authors: | ZHONG Shun He GU Xiu Jun LI Xing Bo XIAO Xiu Fen |
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| Institution: | ZHONG Shun He *,GU Xiu Jun,LI Xing Bo,XIAO Xiu Fen |
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| Abstract: | The title catalyst was prepared by the sol gel method. The surface composite, structure, specific area and catalytic behavior have been investigated by IR, BET, XRD, TEM techniques. The results showed that the catalyst is an amorphous composed of FePO 4 and AlPO 4 with specific area about 238 m 2/g and average granule size less than 10 nm. Under proper reaction conditions the conversion of 1,2 dichloropropane was more than 64% and the selectivity to propylene oxide was more than 79%. |
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| Keywords: | dichloropropane dechlorination oxidation propylene oxide Fe 1/2 Al 1/2 PO 4 |
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