| N-杂环卡宾催化选择性有机反应的新进展 |
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| 引用本文： | 蔡小华,谢兵.N-杂环卡宾催化选择性有机反应的新进展[J].应用化学,2013,30(2):123-133. |
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| 作者姓名： | 蔡小华 谢兵 |
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| 作者单位： | (贵州民族大学化学与环境科学学院 贵阳 550025) |
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| 基金项目： | 国家自然科学基金资助项目，贵阳市科技计划项目 |
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| 摘 要： | 近年来，有关N-杂环卡宾(NHC)的合成、催化性能及其应用得到了快速发展，特别是在催化选择性有机反应领域，NHC类催化剂显示出催化效率高、选择性好及性能优异等特点，而引起人们极大的关注。 本文从区域选择性、顺反异构选择性及手性选择性等方面综述了NHC催化选择性有机反应的最新进展，并予以了展望。
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| 关 键 词： | N-杂环卡宾 选择性有机反应 区域选择性 非对映选择性 立体选择性 |
| 收稿时间： | 2012-07-10 |
| 修稿时间： | 2012-08-21 |
Recent Progress in the Selective Organic Reactions Catalyzed by N-Heterocyclic Carbene |
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| CAI Xiaohua
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XIE Bing.Recent Progress in the Selective Organic Reactions Catalyzed by N-Heterocyclic Carbene[J].Chinese Journal of Applied Chemistry,2013,30(2):123-133. |
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| Authors: | CAI Xiaohua XIE Bing |
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| Institution: | (College of Chemistry and Environmental Science,Guizhou Minzu University,Guiyang 550025,China) |
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| Abstract: | In recent years, rapid developments in the synthesis, catalytic properties and application of N-heterocyclic carbene(NHC) have been achieved. Especially, in selective catalytic organic reactions, NHCs have shown high efficiency, good selectivity and excellent catalytic properties, and therefore have attracted great attention. This review briefly introduced the recent progress on the selective organic reactions catalysed by NHC from the perspectives of regioselectivity, diastereoselectivity and enantioselectivity. The prospects were described. |
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| Keywords: | N-heterocyclic carbene selective organic reaction regioselectivity diastereoselectivity enantioselectivity |
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