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STM studies on adsorbed liquid crystal on HOPG
作者姓名:徐庆敏  谭忠印  王琛  马金  杨林静  李清  朱传凤  王乃新  白春礼
作者单位:1. Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080,China; 2. Department of Chemistry,Liaoning Normal University,Da
基金项目:ProjectsupportedbytheNationalNaturalScienceFoundationofChina (GrantNo .196 34 0 10 )
摘    要:Scanningtunnelingmicroscope(STM)hasrecentlybeenappliedtothestudyoftheadsorptionoforganicandbiologicalmoleculesinvariousenvironments,includingliquidcrystal(LC),onsurface.Inparticular,4_n_alkyl4′cyanobiphenyls(mCB,wheremisthenumberofcarbonsinthealkylgroup)on…

收稿时间:4 April 1998

STM studies on adsorbed liquid crystal on HOPG
Qingmin Xu,Zhongyin Tan,Chen Wang,Jin Ma,Linjing Yang,Qing Li,Chuanfeng Zhu,Naixin Wang,Chunli Bai.STM studies on adsorbed liquid crystal on HOPG[J].Science in China(Chemistry),1998,41(6):640-645.
Authors:Qingmin Xu  Zhongyin Tan  Chen Wang  Jin Ma  Linjing Yang  Qing Li  Chuanfeng Zhu  Naixin Wang  Chunli Bai
Institution:(1) Institute of Chemistry, Chinese Academy of Sciences, 100080 Beijing, China;(2) Department of Chemistry, Liaoning Normal University, 116029 Dalian, China
Abstract:The adsorbed structures of 4-penty14’-methoxy-phenylbenzoate on highly oriented pyrolytic graphite (HOPG) are studied by scanning tunneling microscope (STM) at room temperature with near atomic level resolution. It is observed that the STM images could reveal the regular two-dimensional arrangement of molecules. The computer calculation is performed to determine the contrast mechanism of the STM images associated with the tip-to-sample electric field. The results indicate that the STM images of the liquid crystal may be jointly affected by the modulation of the local work function of the substrate covered with the polarizable molecular adsorbates and the variation of density of states of the adsorbed molecules. Project supported by the National Natural Science Foundation of China (Grant No. 19634010)
Keywords:liquid crystal  STM  molecular simulation  
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