水溶液电解新阴极材料Ni-Co-S-Mo合金的研究 |
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引用本文: | 谢原寿,柳全丰.水溶液电解新阴极材料Ni-Co-S-Mo合金的研究[J].电化学,1998,4(4):434-438. |
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作者姓名: | 谢原寿 柳全丰 |
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作者单位: | 湘潭大学化学化工学院 |
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摘 要: | 多年来,人们对催化析氢阴极材料已进行了不少研究[1~12].其中Pt、Pd等贵金属价格昂贵,不如Raney Ni和过渡金属容易在实际生产中应用[4~12].由于Raney Ni的制备还要将合金中的Al或Zn溶出,形成多孔结构,故其机械强度较差.在过渡...
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关 键 词: | 催化析氢 阴极材料 析氢阴极 镍钴硫钼合金 |
收稿时间: | 1998-11-28 |
Study on Ni Co S Mo Alloys New Cathode Material for Aquous Electrolysis |
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Institution: | College of chemistry & Chemical Engineering Xiang tan University Xiangtan 41105 |
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Abstract: | The parameters of electrodeposion of Ni Co S Mo alloy were studied. The experimental results indicate that the electrodeposition alloy shows high catalytic activity for hydrogen evolution reaction, as well as better mechanical strength and higher chemical stability. The mechanism of catalytic hydrogen evolution reaction on this type of alloy electrode was also investigated by means of polarization curve and cyclic voltametry. |
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Keywords: | Cathode material Ni Co S Mo electrodeposition alloy hydrogen evolution reaction Catalytic activity |
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