| 新型单膦配位羧酸银配合物的合成、表征及其热稳定性的研究(英) |
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| 引用本文： | 韩建林,杨宝海,颜黎均,沈应中,潘毅.新型单膦配位羧酸银配合物的合成、表征及其热稳定性的研究(英)[J].无机化学学报,2005,21(11):1710-1714. |
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| 作者姓名： | 韩建林 杨宝海 颜黎均 沈应中 潘毅 |
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| 作者单位： | 南京大学化学化工学院,配位化学国家重点实验室,南京,210093 |
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| 基金项目： | 国家863计划项目，江苏省精细石油化工重点实验室经费资助。 |
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| 摘 要： | 0 IntroductionIn recent years, silver carboxylates have attractedmany interests, mostly because they are promisingcandidates in the growth of metal thin films via metal-organic chemical vapor deposition (MOCVD) tech-niques. These sliver compounds show low light sensi-tivity and relatively high thermal stability. Several ex-amples of bisphosphine ligands coordinated silver car-boxlylates have been reported1￣4].Monophosphine coordinated silver complexes areexpected to have better volatility,…
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| 关 键 词： | 羧酸银配合物 膦 CVD TG |
| 文章编号： | 1001-4861(2005)11-1710-05 |
| 收稿时间： | 2005-06-13 |
| 修稿时间： | 2005-08-23 |
New Monophosphine Coordinated Silver Carboxylates: Synthesis, Characterization and Thermal Stability |
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| HAN Jian-Lin,YANG Bao-Hai,YAN Li-Jun,SHEN Ying-Zhong and PAN Yi.New Monophosphine Coordinated Silver Carboxylates: Synthesis, Characterization and Thermal Stability[J].Chinese Journal of Inorganic Chemistry,2005,21(11):1710-1714. |
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| Authors: | HAN Jian-Lin YANG Bao-Hai YAN Li-Jun SHEN Ying-Zhong and PAN Yi |
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| Institution: | State Key Lab of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093,State Key Lab of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093,State Key Lab of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093,State Key Lab of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 and State Key Lab of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 |
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| Abstract: | A new series of diphenyl(2-methoxyphenyl)phosphine coordinated silver carboxylates Ag(O2CR)(L): L=Diphenyl(2-methoxyphenyl)phosphine, R=CH3 (3a), CH3CH2 (3b), i-Pr (3c), EtOCH2 (3d), p-CH3OPh (3e), CH3CH=CH (3f), (CH3)2C=CH (3g), ClCH2 (3h)] were synthesized by reaction of diphenyl(2-methoxyphenyl)phosphine with the related silver carboxylates in chloroform. The complexes were obtained as white solids in high yields and their structures have been characterized by elemental analysis, 1H NMR, 13C NMR, 31P NMR, IR spectroscopy. The thermal stability of these complexes has been studied by the TG analysis. These complexes can be used in the growth of metal thin films via aerosol-assisted chemical vapor deposition (AACVD) techniques. |
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| Keywords: | silver carboxylates phosphine CVD TG |
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