| 一个双核锌配合物[(ZnCl2)(PyBIm)]2的合成及结构 |
| |
| 引用本文： | 张全争,聂江辉,周 旭,鲁红典,田长安,赵娣芳.一个双核锌配合物[(ZnCl2)(PyBIm)]2的合成及结构[J].无机化学学报,2011,27(6):1229-1232. |
| |
| 作者姓名： | 张全争 聂江辉 周 旭 鲁红典 田长安 赵娣芳 |
| |
| 作者单位： | 1. 合肥学院化学与材料工程系,合肥,230022;中国科学院福建物质结构研究所结构化学国家重点实验室,福州,350002
2. 合肥学院化学与材料工程系,合肥,230022 |
| |
| 基金项目： | 结构化学国家重点实验室基金，安徽省自然科学基金 |
| |
| 摘 要： | 在水热条件下，合成了1个新的双核锌配合物(ZnCl2)(PyBIm)]2(PyBIm=2-(4-pyridyl)benzimidazole)。该配合物为单斜晶系，P21/n空间群，晶胞参数a=0.774 51(4) nm，b=1.252 49(5) nm，c=1.315 96(7) nm，β=100.294(3)°，V=1.256 0(1) nm3，Z=2。结构分析表明，Zn被2个Cl原子和来自PyBIm配体的2个N原子配位，形成了1个变形四面体结构。在该配合物中，Zn…Zn距离为 0.709 4(5) nm，结构中存在π…π堆积和氢键作用。
|
| 关 键 词： | 锌 2-(4-吡啶基)苯并咪唑 晶体结构 |
Synthesis and Structure of a Binuclear Zinc Complex [(ZnCl2)(PyBIm)]2 |
| |
| ZHANG Quan-Zheng,NIE Jiang-Hui,ZHOU Xu,LU Hong-Dian,TIAN Chang-An and ZHAO Di-Fang.Synthesis and Structure of a Binuclear Zinc Complex [(ZnCl2)(PyBIm)]2[J].Chinese Journal of Inorganic Chemistry,2011,27(6):1229-1232. |
| |
| Authors: | ZHANG Quan-Zheng NIE Jiang-Hui ZHOU Xu LU Hong-Dian TIAN Chang-An and ZHAO Di-Fang |
| |
| Institution: | Department of Chemistry & Materials Engineering, Hefei University, Hefei 230022, China; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China,Department of Chemistry & Materials Engineering, Hefei University, Hefei 230022, China,Department of Chemistry & Materials Engineering, Hefei University, Hefei 230022, China,Department of Chemistry & Materials Engineering, Hefei University, Hefei 230022, China,Department of Chemistry & Materials Engineering, Hefei University, Hefei 230022, China and Department of Chemistry & Materials Engineering, Hefei University, Hefei 230022, China |
| |
| Abstract: | A new binuclear zinc complex(ZnCl2)(PyBIm)]2(PyBIm=2-(4-pyridyl)bemimidazole)has been synthesized by hydrothermal reaction.The complex crystallizes in triclinic P21/n space group with crystal cell parameters of a=0.774 51(4)nm,b=1.252 49(5)nm,c=1.315 96(7)am,β=100.294(3)°,V=I.2560(1)nm3 and Z=2.The crystal X-ray analysis shows that Zn atom is coordinated by two C1 atoms and two N atoms from two PyBIm ligands in a interactions also exist in the structure.CCDC:800921. |
| |
| Keywords: | zinc 2-(4-pyridyl)benzimidazole crystal structure |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
| 点击此处可从《无机化学学报》浏览原始摘要信息 |
| 点击此处可从《无机化学学报》下载免费的PDF全文 |
|
