| 配位聚合物{[CoL][FeⅡFeⅢ(ox)3·1.5H2O]}∞的合成、波谱表征和磁学性质 |
| |
| 引用本文： | 陈友存,刘光祥,周宏,徐衡.配位聚合物{[CoL][FeⅡFeⅢ(ox)3·1.5H2O]}∞的合成、波谱表征和磁学性质[J].无机化学学报,2003,19(1):103-106. |
| |
| 作者姓名： | 陈友存 刘光祥 周宏 徐衡 |
| |
| 作者单位： | 安庆师范学院化学系,安庆,246011 |
| |
| 基金项目： | 国家自然科学基金资助项目(No.20171001)，安徽省科技厅“十五”攻关项目(No.01012038)，安徽省教育厅基金资助项目(No.200lkj162)。 |
| |
| 摘 要： | A new Schiff base complex， CoL(ClO4)·3H2O (1) {L represents condensed from equal molar ratio of sali-cylaldehyde and diethylenetriamine} was synthesized and characterized. Further， a new coordination polymer， {CoL]FeⅡFeⅢ(ox)3·1.5H2O]}∞ (2)， was synthesized and characterized， where ox2-=oxalate. The results of the IR and M?ssbauer spectra of 2 revealed that the coordination polymer exists 2-D layer structure in the solid state， and anions layer was formed by ⅡFeⅢ(ox)3]- unit. The magnetic properties of 2 have been measured and the results indicate that there is magnetic ordering in the low temperature， which may arise from intermolecular ferromagnetic interactions or spin canted effects.
|
| 关 键 词： | 草酸根桥联 配位聚合物 合成 波谱表征 磁学性质 |
| 修稿时间： | 2002年8月16日 |
Coordination Polymer {[CoL] [FeⅡFeⅢ (ox)3·1.5H2O] }∞: Syntheses, Spectra Characterization and Magnetic Properties |
| |
| CHEN You-Cun,LIU Guang-Xiang,ZHOU Hong and XU Heng.Coordination Polymer {[CoL] [FeⅡFeⅢ (ox)3·1.5H2O] }∞: Syntheses, Spectra Characterization and Magnetic Properties[J].Chinese Journal of Inorganic Chemistry,2003,19(1):103-106. |
| |
| Authors: | CHEN You-Cun LIU Guang-Xiang ZHOU Hong and XU Heng |
| |
| Abstract: | |
| |
| Keywords: | bridging oxalate coordination polymer synthesis spectra characterization magnetic properties |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
| 点击此处可从《无机化学学报》浏览原始摘要信息 |
| 点击此处可从《无机化学学报》下载免费的PDF全文 |
