| 新型双核席夫碱配合物的合成及谱学性质 |
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| 引用本文： | 张玉玲,阮文娟,胡国航,朱志昂.新型双核席夫碱配合物的合成及谱学性质[J].无机化学学报,2002,18(9):902-906. |
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| 作者姓名： | 张玉玲 阮文娟 胡国航 朱志昂 |
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| 作者单位： | 南开大学化学系,天津,300071 |
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| 基金项目： | 国家自然科学基金资助项目(No.20171024)，教育部留学回国人员科研基金资助项目。 |
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| 摘 要： | Eight novel binuclear tetradentate Schiff base complexes (M=Cu(Ⅱ),Ni(Ⅱ),Zn(Ⅱ)) are synthesized. The structure of complexes is two discrete Schiff base unit bridged. The complexes were condensed from series sub-stituent Ketones (5-chloro-2-hydroxybenzophenone, 5-methyl-2-hydroxy-benzophenone, 5-Bromo-2-hydroxybenzop- henone) and dialdehydes (5,5′-methylene-disalicylaldehyde) with the amino group of 1,2-diaminobenzene, and by Metal ion as template. The compounds were characterized by elemental analyses, FT-infrared spectra, Raman, 1H NMR, UV-vis electronic spectra, EPR spectra. The FT-infrared spectra and Raman spectra of complexes were compared and discussed. The UV-vis election spectra, 1H NMR and EPR spectra of complexes have also been attributed and minutely analyzed.
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| 关 键 词： | 席夫碱 双核配合物 合成和性质 |
| 修稿时间： | 2002年2月21日 |
Synthesis and Spectra Properties of Novel Binuclear Schiff Base Complexes |
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| ZHANG Yu-Ling,RUAN Wen-Juan,HU Guo-Hang and ZHU Zhi-Ang.Synthesis and Spectra Properties of Novel Binuclear Schiff Base Complexes[J].Chinese Journal of Inorganic Chemistry,2002,18(9):902-906. |
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| Authors: | ZHANG Yu-Ling RUAN Wen-Juan HU Guo-Hang and ZHU Zhi-Ang |
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| Institution: | Department of Chemistry, Nankai University, Tianjin 300071,Department of Chemistry, Nankai University, Tianjin 300071,Department of Chemistry, Nankai University, Tianjin 300071 and Department of Chemistry, Nankai University, Tianjin 300071 |
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| Abstract: | |
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| Keywords: | Schiff base binuclear complexes syntheses and properties |
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