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有机杂化锑基主族异金属硫属化物的研究进展
引用本文:冯美玲,黄小荥.有机杂化锑基主族异金属硫属化物的研究进展[J].无机化学学报,2013,29(18).
作者姓名:冯美玲  黄小荥
作者单位:中国科学院福建物质结构研究所, 结构化学国家重点实验室, 福州 350002;中国科学院福建物质结构研究所, 结构化学国家重点实验室, 福州 350002
基金项目:973项目(No.2012CB821702); 国家自然科学基金(No.21171164 and 21221001); 福建省自然科学基金(No.2010J01056)资助项目。
摘    要:本文综述了有机杂化锑基主族异金属硫属化物的研究进展, 对它们的结构和异金属次级结构基元进行了描述、归类和总结;探讨了有机组分分别作为结构导向剂和配体两种角色所起到的不同作用;介绍了这类化合物在离子交换、光催化性能方面的研究;展望了该体系的发展趋势。

关 键 词:  主族金属  硫属化物  晶体结构  次级结构基元  离子交换  光催化

Recent Progress in Organic Hybrid Main Group Heterometallic Chalcogenides Based on Antimony
FENG Mei-Ling and HUANG Xiao-Ying.Recent Progress in Organic Hybrid Main Group Heterometallic Chalcogenides Based on Antimony[J].Chinese Journal of Inorganic Chemistry,2013,29(18).
Authors:FENG Mei-Ling and HUANG Xiao-Ying
Institution:State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002;State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002
Abstract:In this review, the recent research progress of organic hybrid main group heterometallic chalcogenides based on antimony has been summarized. The structures and typical secondary building units of these compounds are described and classified. The roles of organic constituents as structure-directing agents or ligands are explored. The studies on their ion-exchange and photocatalytic properties are reviewed.
Keywords:antimony  main group metal  chalcogenide  crystal structure  secondary building unit  ion-exchange  photocatalytic property
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