| 含双咪唑配体的锌配位聚合物的晶体结构、荧光性质及抑菌性能研究 |
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| 引用本文： | 周先礼,张秉君,王萃娟,黄 帅,邱光美,王尧宇.含双咪唑配体的锌配位聚合物的晶体结构、荧光性质及抑菌性能研究[J].无机化学学报,2012,28(8):1736-1742. |
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| 作者姓名： | 周先礼 张秉君 王萃娟 黄 帅 邱光美 王尧宇 |
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| 作者单位： | 1. 西南交通大学生命科学与工程学院化学化工系,成都,610031
2. 西北大学化学与材料学院,合成与天然功能分子化学教育部重点实验室,西安710069 |
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| 基金项目： | 国家自然科学基金，新世纪优秀人才基金，中央高校基本科研业务费专项资金，西南交通大学科学研究基金 |
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| 摘 要： | 本文报道了一个基于双咪唑配体的锌配位聚合物Zn(oxa)(bbi)]n(1)(oxa=草酸,bbi=1,1′-(1,4-丁二基)双咪唑),并对该化合物进行元素分析、红外和X-射线单晶衍射分析。结果表明标题化合物通过配位键和π-π堆积作用力形成了一个由(4,4)拓扑形状的二维网络组成的具有大孔洞的三维金属有机框架结构。除此之外,测定了配合物1的荧光发射光谱并对其微生物抑菌性能进行了初步研究。
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| 关 键 词： | 1 1′-(1 4-丁二基)双咪唑 配位聚合物 荧光光谱 抑菌性 |
Structural Characterization, Luminescence Behavior and Antimicrobial Study of a Zinc Coordination Polymer Based on Bis(imidazole) Ligand |
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| ZHOU Xian-Li,ZHANG Bing-Jun,WANG Cui-Juan,HUANG Shuai,QIU Guang-Mei and WANG Yao-Yu.Structural Characterization, Luminescence Behavior and Antimicrobial Study of a Zinc Coordination Polymer Based on Bis(imidazole) Ligand[J].Chinese Journal of Inorganic Chemistry,2012,28(8):1736-1742. |
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| Authors: | ZHOU Xian-Li ZHANG Bing-Jun WANG Cui-Juan HUANG Shuai QIU Guang-Mei and WANG Yao-Yu |
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| Institution: | 1Department of Chemistry and Chemical Engineering,School of Life Science and bioengineering, Southwest JiaoTong University,Chengdu 610031,China)(2Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Department of Chemistry,Northwest University,Xi′an 710069,China) |
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| Abstract: | A coordination polymer based on zinc(Ⅱ) and mixed ligands Zn(oxa)(bbi)]n(1)(oxa=oxalate anion,bbi=1,1′-(1,4-butanediyl)bis(imidazole)),has been prepared and characterized by single-crystal X-ray diffraction.The structure of polymer 1 presents an unique two-dimensional(2D) layer structure with(4,4) topology in the presence of meso-helical chains and a three-dimensional(3D) network distorted with large channels.In addition,moderate fluorescent emission in the solid state at room temperature was observed in the Zn1-containing polymeric compound 1.And antimicrobial activity of the compound has been investigated.CCDC: 842497. |
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| Keywords: | 1 1'-(1 4-Butanediyl)bis(imidazole) coordination polymer fluorescence spectrum antimicrobial activity |
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