| 基于2-苯基-4-喹啉酸及双咪唑类配体的钴(Ⅱ)配合物的合成、表征、磁性和电化学性质 |
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| 引用本文： | 侯向阳,王潇,付峰,王记江,唐龙.基于2-苯基-4-喹啉酸及双咪唑类配体的钴(Ⅱ)配合物的合成、表征、磁性和电化学性质[J].无机化学学报,2013,29(10):2245-2250. |
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| 作者姓名： | 侯向阳 王潇 付峰 王记江 唐龙 |
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| 作者单位： | 延安大学化学与化工学院陕西省化学反应过程重点实验室,延安,716000 |
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| 基金项目： | 陕西省教育厅科研计划项目(No.11JK0583),陕西省科学技术研究发展计划(No.2013JM2015)资助项目 |
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| 摘 要： | 利用2-苯基-4-喹啉酸、苯-1,4-双(咪唑基-1-甲基)和乙酸钴在二甲基甲酰胺和水的混合溶剂中反应,得到配合物Co(pqba)2(biyb)](1)(Hpqba=2-苯基-4-喹啉酸,biyb=苯-1,4-双(咪唑基-1-甲基))。采用元素分析、红外光谱、X单晶衍射结构分析、热重分析等方法对配合物进行了表征和结构测定。配合物1属单斜晶系,C2/c空间群。配合物1中的biyb配体采用双齿桥链模式连接金属钴离子首先形成一维"之"字链,通过π…π堆积作用,进一步拓展为二维超分子结构。循环伏安法测试结果说明配合物1的电解过程为准可逆过程。磁化率测量表明,配合物1具有反铁磁性质。
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| 关 键 词： | 钴配合物 晶体结构 磁性质 电化学性质 |
| 收稿时间： | 2013/1/29 0:00:00 |
| 修稿时间： | 2013/4/30 0:00:00 |
Syntheses, Characterizations, Magnetic Susceptibility, and Electrochemical Property of Cobalt Complex Based on 2-Phenyl-4-quinolinecarboxylic Acid and Imidazol-Based Linker |
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| HOU Xiang-Yang,WANG Xiao,FU Feng,WANG Ji-Jiang and TANG Long.Syntheses, Characterizations, Magnetic Susceptibility, and Electrochemical Property of Cobalt Complex Based on 2-Phenyl-4-quinolinecarboxylic Acid and Imidazol-Based Linker[J].Chinese Journal of Inorganic Chemistry,2013,29(10):2245-2250. |
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| Authors: | HOU Xiang-Yang WANG Xiao FU Feng WANG Ji-Jiang and TANG Long |
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| Institution: | Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Yan'an, Shaanxi 716000, China;Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Yan'an, Shaanxi 716000, China;Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Yan'an, Shaanxi 716000, China;Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Yan'an, Shaanxi 716000, China;Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Yan'an, Shaanxi 716000, China |
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| Abstract: | |
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| Keywords: | cobalt complex crystal structure magnetic susceptibility electrochemical property |
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