| 双核Cd(Ⅱ)-8-喹啉氧基乙酸根离子配合物的合成与晶体结构 |
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| 引用本文： | 王玉红,赵凯元,杜鹃.双核Cd(Ⅱ)-8-喹啉氧基乙酸根离子配合物的合成与晶体结构[J].无机化学学报,2005,21(4):511-514. |
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| 作者姓名： | 王玉红 赵凯元 杜鹃 |
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| 作者单位： | 苏州科技学院化学化工系,苏州,215009 |
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| 基金项目： | 江苏省普通高校自然科学研究计划资助项目(No.03KJD150203)，苏州科技学院院级项目资助。 |
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| 摘 要： | A novel cadmium(Ⅱ) complex with 8-quinolinyloxyacetate has been prepared and characterized by X-ray diffraction. The complex is a centrosymmetric Cd2L2Cl4(MeOH)2] dinuclear structure and the Cd(Ⅱ) centre is in a distorted octahedron geometry. The crystal is in triclinic system, space group P1, with a=0.752 2(4) nm, b=1.043 1(5) nm, c=1.097 3(6) nm, α=66.11(2)°, β=72.48(2)°, γ=70.28(2)° and Z=1. The most striking feature of this complex is the formation of a 3D network bridged through the intermolecular N-H…O, O-H…O, C-H…O and C-H…Cl hydrogen bonds and stabilized via intermolecular π-π stacking interactions. CCDC: 224677.
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| 关 键 词： | 晶体结构 8-喹啉氧基乙酸 Cd(Ⅱ)配合物 氢键 |
| 文章编号： | 1001-4861(2005)04-0511-04 |
| 收稿时间： | 2004/8/30 0:00:00 |
| 修稿时间： | 2004年8月30日 |
Synthesis and Crystal Structure of Dinuclear Cd(Ⅱ) Complex with 8-quinolinyloxyacetate |
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| WANG Yu-Hong,ZHAO Kai-Yuan and DU Juan.Synthesis and Crystal Structure of Dinuclear Cd(Ⅱ) Complex with 8-quinolinyloxyacetate[J].Chinese Journal of Inorganic Chemistry,2005,21(4):511-514. |
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| Authors: | WANG Yu-Hong ZHAO Kai-Yuan and DU Juan |
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| Institution: | Department of chemistry and chemical engineering, Suzhou College of Science and Technology, Suzhou 215009,Department of chemistry and chemical engineering, Suzhou College of Science and Technology, Suzhou 215009 and Department of chemistry and chemical engineering, Suzhou College of Science and Technology, Suzhou 215009 |
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| Abstract: | |
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| Keywords: | crystal structure 8-quinolinyloxyacetic acid Cd complex hydrogen bonds |
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